Dess-Martin Periodinane (Technical Grade)

CAS: 87413-09-0

Ref. TR-D297420

Product Information

• Name: Dess-Martin Periodinane (Technical Grade)
• Synonyms: Acetic Acid 1,1',1''-(3-Oxo-1lambda5-1,2-benziodoxol-1(3H)-ylidyne) Ester, 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one, Dess-Martin Reagent, Martin's Reagent, Triacetoxyperiodinane, DMP, (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one, (1,1-Diacetoxy-3-oxo-1,2-benziodoxol-1-yl) acetate, 1,1,1-tris(acetyloxy)-1lambda~5~,2-benziodoxol-3(1H)-one, 1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one, 1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-, Acetic acid, 1,1′,1′′-(3-oxo-1λ⁵-1,2-benziodoxol-1(3H)-ylidyne) ester, Dess-martin, Martin's reagent, Reagents, Martin's, Dess Martin Periodinane, Acetic acid, 1,1′,1′′-(3-oxo-1λ5-1,2-benziodoxol-1(3H)-ylidyne) ester, Dess-Martin periodinane

Description

Applications Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Dess, D.B. et al.: J. Org. Chem., 48, 4155 (1983); Dess, D. B. et al.: J. Am. Chem. Soc., 113, 7277 (1991);

• Brand: TRC

Chemical properties

• Molecular weight: 424.14
• Formula: C₁₃H₁₃IO₈
• Color/Form: White To Beige
• InChI: InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
• InChI key: InChIKey=NKLCNNUWBJBICK-UHFFFAOYSA-N
• SMILES: CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc21