(1R,3R,4R)-(-)-3,5-Dinitrobenzoate Menthol
CAS: 1195710-85-0
Ref. TR-D480025
| 50mg | 169.00 € | ||
| 100mg | 245.00 € | ||
| 250mg | 471.00 € |
Estimated delivery in United States, on Monday 23 Dec 2024
Product Information
Name:
(1R,3R,4R)-(-)-3,5-Dinitrobenzoate Menthol
Controlled Product
Synonyms:
- 7-[(2S,5R)-6-[[tert-butyl(diphenyl)silyl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-4-methylchromen-2-one
Description:
Applications (1S,3S,4S)-(-)-3,5-dinitrobenzoate Menthol is an intermediate in the synthesis of (±)-Neoisomenthol (N389960) which is a useful synthetic intermediate. It is used to prepare alkyl and aryl esters by chemoselective acylation of alkyl and aryl alcohols with carboxylic acid anhydrides in the presence of magnesium bis(trifluoromethylsulfonyl)amide under solvent-free conditions.
References Chakraborti, A., et al.: J. Org. Chem., 71, 5785 (2006)
Notice:
Our products are intended for lab use only. For any other use, please contact us.
Brand:
TRC
Long term storage:
Notes:
Chemical properties
Molecular weight:
576.709
Formula:
C32H36O8Si
Color/Form:
Neat
InChI:
InChI=1S/C32H36O8Si/c1-20-17-27(33)39-25-18-21(15-16-24(20)25)38-31-30(36)29(35)28(34)26(40-31)19-37-41(32(2,3)4,22-11-7-5-8-12-22)23-13-9-6-10-14-23/h5-18,26,28-31,34-36H,19H2,1-4H3/t26?,28-,29?,30?,31+/m0/s1
InChI key:
InChIKey=YTHDSJIOVBDTQV-OFMPIAEOSA-N
SMILES:
Cc1cc(=O)oc2cc(O[C@@H]3OC(CO[Si](c4ccccc4)(c4ccccc4)C(C)(C)C)[C@H](O)C(O)C3O)ccc12
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