(1-[Ethoxycarbonyl]ethylidene)triphenylphosphoran

CAS: 5717-37-3

Ref. TR-E891540

Product Information

• Name: (1-[Ethoxycarbonyl]ethylidene)triphenylphosphoran
• Synonyms: ((Ethoxycarbonyl)ethylidene)triphenylphosphorane, (Carbethoxyethylidene)triphenylphosphorane, 1-(Ethoxycarbonyl)ethylidenetriphenylphosphorane, 1-Carboethoxyethylidenetriphenylphosphorane, 2-(Triphenylphosphoranylidene)propanoic Acid Ethyl Ester, Ethyl 2-(Triphenylphosphoranylidene)propanoate, Ethyl 2-(Triphenylphosphoranylidene)propionate, Ethyl Methyltriphenylphosphoranylideneacetate, NSC 76468, Triphenyl-alpha-ethoxycarbonylethylidenephosphorane, [alpha-(Ethoxycarbonyl)ethylidene]triphenylphosphorane, alpha-(Ethoxycarbonyl)ethylenetriphenylphosphorane, (1-Carbethoxyethylidene)triphenylphosphorane~(1-Carboethoxyethylidene)triphenylphosphorane~Ethyl 2-(triphenylphosphoranylidene)propionate, (1-Ethoxycarbonylethylethylidene)Triphenylphosporane, (Carbethoxyethylidine)triphenylphosphorane, 2-(Triphenyl-λ*5*-phosphanylidene)-propionic acid ethyl ester, 2-(Triphenylphosphoranylidene)propanoic acid ethyl ester, Carbethoxy Ethylidene Triphenyl Phosphorane, Ceetpp, Ethyl 2-(Triphenyl-Lambda~5~-Phosphanylidene)Propanoate, Ethyl 2-(triphenyl-λ⁵-phosphanylidene)propanoate, Ethyl 2-(triphenylphosphoranylidene)propanoate, Ethyl 2-(triphenylphosphoranylidene)propionate, Ethyl methyltriphenylphosphoranylideneacetate, Propanoic acid, 2-(triphenylphosphoranylidene)-, ethyl ester, Propionic acid, 2-(triphenylphosphoranylidene)-, ethyl ester, Triphenyl-α-ethoxycarbonylethylidenephosphorane, [α-(Ethoxycarbonyl)ethylidene]triphenylphosphorane, methyl (5E)-5-[4-(benzyloxy)benzylidene]-1-(3,5-dimethylphenyl)-2-methyl-4-oxo-4,5-dihydro-1H-pyrrole-3-carboxylate, Α-(Ethoxycarbonyl)Ethylenetriphenylphosphorane

Description

Applications (1-[Ethoxycarbonyl]ethylidene)triphenylphosphoran, is a Horner-Wadsworth-Emmons reagent. It can be used for olefination. It can also be utilized for the synthesis of more complex compounds, such as (29S,37S)-isomer of malevamide E, a potent ion-channel inhibitor.
References Gajula, P., et al.: Org. Biomol. Chem., 11, 257 (2013); Naito, T., et al.: Chem. Pharm. Bull., 44, 624 (1996), Hata, A., et al.: Mol. Pharmacol., 67, 640 (2005),

• Brand: TRC

Chemical properties

• Molecular weight: 362.4
• Formula: C₂₃H₂₃O₂P
• Color/Form: Neat
• InChI: InChI=1S/C23H23O2P/c1-3-25-23(24)19(2)26(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-18H,3H2,1-2H3
• InChI key: InChIKey=KZENFXVDPUMQOE-UHFFFAOYSA-N
• SMILES: CCOC(=O)C(C)=P(c1ccccc1)(c1ccccc1)c1ccccc1