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Trichloro[2-(chloromethyl)-2-propen-1-yl]silane

CAS:

Ref. TR-T294870

5g
1,022.00€
Trichloro[2-(chloromethyl)-2-propen-1-yl]silane
TRC

Product Information

Name:Trichloro[2-(chloromethyl)-2-propen-1-yl]silane
Controlled Product
Synonyms:
  • 2-(Chloromethyl)-3-(trichlorosilyl)propene
  • Trichloro[2-(chloromethyl)allyl]-silane
  • Trichloro[2-(chloromethyl)-2-propenyl]-silane
Brand:TRC
Description:Applications Trichloro[2-(chloromethyl)-2-propen-1-yl]silane is an intermediate used in the synthesis of 2-​(Chloromethyl)​allyl-​trimethylsilane (C371430), which is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-​(Chloromethyl)​allyl-​trimethylsilane was used in catalytic Sakurai reaction of α,​β-​enones.References Kopecky, D., et al.: J. Am. Chem. Soc., 123, 8420 (2001).Lee, P., et al.: J. Org. Chem., 66, 8646 (2001).
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Chemical properties

Molecular weight:223.988
Formula:C4H6Cl4Si
Color/Form:Neat
InChI:InChI=1S/C4H6Cl4Si/c1-4(2-5)3-9(6,7)8/h1-3H2
InChI key:InChIKey=SJFJNNLIAXEOSE-UHFFFAOYSA-N
SMILES:C=C(CCl)C[Si](Cl)(Cl)Cl

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