Tris(triphenylphosphine)rhodium(I) Chloride

CAS: 14694-95-2

Ref. TR-T886465

Product Information

• Name: Tris(triphenylphosphine)rhodium(I) Chloride
• Synonyms: Chlorotris(triphenylphosphine)rhodium, Chlorotris(triphenylphosphine)rhodium(I), NSC 124140, Rhodium tris(triphenylphosphine) chloride, Tris(triphenylphosphine)chlororhodium, Tris(triphenylphosphine)chlororhodium(I), Wilkinson's Catalyst, Wilkinson's Complex, (SP-4-2)-Chlorotris(triphenylphosphine)rhodium, Chlororhodium, Triphenylphosphane, Chlorotris(Triphenylphosphine)Rhodate (I), Chlorotris(Triphenylphosphine)Rhodium, Chlorotris(Triphenylphosphine)Rhodium(I), Decarbon, Nsc 124140, Phosphine, Triphenyl-, Chloride, Rhodium Salt (3:1), Rhodium Tris(Triphenyl-Phosphine)Chloride, Rhodium(I) Tris(Triphenylphosphine) Chloride, Rhodium(I) Tris(Triphenylphosphine) Chloride Polymer Supported, Wilkinsons Catalyst Polymer Supported, Rhodium, chlorotris(triphenylphosphine)-, Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-, Tris(Tripehnylphosphine)Rhodium(I)Chloride, Tris(Triphenylphosphine)Rhodium(1) Chloride, Tris(Triphenylphosphine)Rhodium(I) Chloride Polymer Bound, Tris(triphenylphosphin)rhodium(I)chlorid, Tris(triphenylphosphine)rhodium chloride, Tris(triphenylphosphine)rhodium monochloride, Wilkinson Catalyst, Wilkinson's catalyst, Wilkinson's complex, Wilkinsons catalyst, [Tristriphenylphosphine)Rhodium(I) Chloride], chlorure de tris(triphenylphosphine)rhodium (I), cloruro de tris(trifenilfosfina)rodio (I)

Description

Applications Tris(triphenylphosphine)rhodium Chloride is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodium(I) Chloride is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.
References Evans, D.A. et al.: J. Am. Chem. Soc., 110, 6917 (1988); Ojima, I. et al.: Tetrahedron Lett., 13, 5035 (1972); Birch, A.J. et al.: Org. React., 24 (1976);

• Brand: TRC

Chemical properties

• Molecular weight: 925.21
• Formula: C₅₄H₄₅ClP₃Rh
• Color/Form: Neat
• InChI: InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1
• InChI key: InChIKey=QBERHIJABFXGRZ-UHFFFAOYSA-M
• SMILES: [Cl-].[Rh].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1