CAS 498-07-7

1,6-anhidro-β-D-glicose

Descrição:

1,6-anhidro-β-D-glicose é um derivado de açúcar cíclico caracterizado por sua estrutura única, que apresenta um anel de seis membros formado pela desidratação de dois grupos hidroxila nas posições 1 e 6 do β-D-glicose. Este composto é um sólido cristalino branco que é solúvel em água, refletindo sua natureza polar devido à presença de grupos hidroxila. É comumente encontrado em vários polissacarídeos naturais, particularmente na estrutura de certos materiais vegetais e como produto da degradação da celulose. A forma anidra indica que falta uma molécula de água que normalmente estaria presente em sua forma hidratada, o que influencia sua reatividade e estabilidade. 1,6-anhidro-β-D-glicose pode participar de várias reações químicas, incluindo glicosilação e oxidação, tornando-o de interesse tanto em aplicações bioquímicas quanto industriais. Seu papel na química de carboidratos e as aplicações potenciais em farmacêuticos e ciência dos alimentos destacam sua importância em processos naturais e sintéticos.

Fórmula: C₆H₁₀O₅

InChI: InChI=1/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2/t2-,3+,4-,5+,6-/m0/s1

Chave InChI: InChIKey=TWNIBLMWSKIRAT-VFUOTHLCSA-N

SMILES: O[C@@H]1[C@@]2(O[C@@](OC2)([C@H](O)[C@H]1O)[H])[H]

Sinónimos:

• 1,6-Anhydro-<span class="text-smallcaps">D</span>-glucopyranoside
• 1,6-Anhydro-<span class="text-smallcaps">D</span>-glucose
• 1,6-Anhydro-Beta-D-Glucopyranose
• 1,6-Anhydro-D-glucopyranoside
• 1,6-Anhydro-D-glucose
• 1,6-Anhydro-β-<span class="text-smallcaps">D</span>-glucopyranose
• 1,6-Anhydro-β-<span class="text-smallcaps">D</span>-glucose
• 1,6-Anhydro-β-D-glucopyranose
• 1,6-Anhydroglucose
• 1,6-anhidro-β-D-glucosa
• 6,8-Dioxabicyclo[3.2.1]octane, β-<span class="text-smallcaps">D</span>-glucopyranose deriv.
• <span class="text-smallcaps">D</span>-Glucose, 1,6-anhydro-
• D-Glucose, 1,6-anhydro-
• GLUCOPYRANOSE (,beta.-D), 1,6-ANHYDRO-
• Leucoglucosan
• Levoglucosan
• Nsc 46243
• β-<span class="text-smallcaps">D</span>-Glucopyranose, 1,6-anhydro-
• β-D-Glucopyranose, 1,6-anhydro-
• 6,8-Dioxabicyclo[3.2.1]octane, β-D-glucopyranose deriv.
• (-)-1,6-ANHYDRO-B-D-GLUCOPYRANOSE FOR SY
• 1,6-Anhydro-beta-D-glucopyranose, 99+%
• 1,6-Anhydro-β-D-glucose ,98%
• 1,6-Anhydro-?-glucopyranose
• 1,6-anhydro-á-d-glucopyranose
• 1,6-ANHYDRO-SS-D-GLUCOPYRANOSE, 99% MIN., HPLC
• 1,6-anhydro-β-d-[1-2H]glucose
• beta-D-Glucopyranose, 1,6-anhydro-
• Laevoglucosan
• 1,6-Anhydro-beta-D-glucopyranose (levoglucosan)
• 1,6-Anhydro-D-glucopyranose, 99℉
• 1,6-Anhydro-
• 1,6-Anhydro-β-D-glucose,Levoglucosan
• (-)-1,6-Anhydro--D-glucopyranose for synthesis
• 1,6-Anhydro-beta-D-glucopyranose min. 98%
• 1,6-Anhydro-β-D-glycopyranose
• 1,6-Anhydro-beta-D-glucose 99%
• 1,6-ANHYDRO-BETA-D-GLUCOSE (LEVOGLUCOSAN)
• 1,6-ANHYDRO-SS-D-GLUCOPYRANOSE
• 1,6-anhydro-beta-glucopyranose
• 1,6-ANHYDRO-BETA-D-GLUCOPYRA
• 1,6-ANHYDRO-BETA-D-GLUCOSE
• 1,6-anhydro-β-d-[UL-2H7]glucose
• 1,6-anhydro-beta-d-glucopyranos
• 1,6-anhydro-D-glucose (50 mg)
• 1,6-Dideoxy-1,6-epoxy-β-D-glucopyranose
• 1,6-Anhydro-β-glucopyranose
• 1,6-ANHYDRO-B-D-GLUCOSE

1,6-Anhydro-β-D-glucose

CAS: 498-07-7

Fórmula: C₆H₁₀O₅

Pureza: >99.0%(GC)

Cor e Forma: White to Light yellow powder to crystal

Peso molecular: 162.14

Ref: 3B-A1074

1,6-Anhydro-β-D-glucopyranose, 99%

CAS: 498-07-7

1,6-Anhydro-beta-D-glucopyranose is used for the preparation of biologically important and structurally diverse products such as rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, macrolide antibiotics and modified sugars. It is used as a chemical tracer for biomass burning

Fórmula: C₆H₁₀O₅

Pureza: 99%

Cor e Forma: Powder or crystals or crystalline powder, White

Peso molecular: 162.14

Ref: 02-A16724

1,6-anhydro-D-glucose

CAS: 498-07-7

Heterocyclic compounds with oxygen hetero-atom(s) only, nesoi

Fórmula: C₆H₁₀O₅

Cor e Forma: White Beige Powder

Peso molecular: 162.05282

Ref: 45-1035300

b-D-Glucopyranose, 1,6-anhydro-

CAS: 498-07-7

Fórmula: C₆H₁₀O₅

Pureza: 98%

Cor e Forma: Solid

Peso molecular: 162.1406

Ref: IN-DA00I8WB

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

1,6-Anhydro-β-D-glucopyranose

Fórmula: C₆H₁₀O₅

Pureza: 98%

Cor e Forma: Beige Solid

Peso molecular: 162.1406

Ref: 54-OR4810T

Levoglucosan

CAS: 498-07-7

Levoglucosan

Fórmula: C₆H₁₀O₅

Pureza: ≥95%

Peso molecular: 162.14

Ref: 54-BUP18060

Levoglucosan

Produto Controlado

CAS: 498-07-7

Fórmula: C₆H₁₀O₅

Cor e Forma: Neat

Peso molecular: 162.14

Ref: 04-C14629735

Levoglucosan (Standard)

CAS: 498-07-7

Levoglucosan (Standard) is the standard substance of Levoglucosan, and it is applicable for quantitative analysis, quality control, and related research in biochemical experiments. Levoglucosan (1,6-anhydro-b-D-Glucose) is an anhydrohexose that is the 1,6-anhydro-derivative of beta-D-glucopyranose. It is formed from the pyrolysis of carbohydrates, such as starch and cellulose. Levoglucosan can also be utilized in the synthesis of chiral polymers such as unhydrolysable glucose polymers. Levoglucosan is also produced via caramelization of sugar. Consumption of caramel or caramel-containing sweets can lead to a short-term 5X increase in urinary levels of levoglucosan (from 20 uM/mM creatinine to 100 uM/mM creatinine).

Fórmula: C₆H₁₀O₅

Cor e Forma: Solid

Peso molecular: 162.14

Ref: TM-TMSM-1457

Levoglucosan

CAS: 498-07-7

Levoglucosan is a byproduct of carbohydrate pyrolysis, used in chiral polymer synthesis, and increases in urine post-caramel consumption.

Fórmula: C₆H₁₀O₅

Pureza: 99.92% - ≥95%

Cor e Forma: Solid

Peso molecular: 162.14

Ref: TM-T5250

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

1,6-Anhydro-β-D-glucopyranose

Fórmula: C₆H₁₀O₅

Pureza: 98%

Cor e Forma: Solid-Powder

Peso molecular: 162.1406

Ref: 54-BICL4018

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

Fórmula: C₆H₁₀O₅

Pureza: (HPLC) ≥ 99.0%

Cor e Forma: White crystalline powder

Peso molecular: 162.14

Ref: 7W-GC5907

1,6-Anhydro-β-D-glucopyranose

CAS: 498-07-7

Stability Hygroscopic
Applications 1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.The chemical/physical/toxicological properties have not been thoroughly investigated. Since it is known to be a minor component of certain food materials it may be regarded as of relatively low toxicity.
References Fraser-Reid, B., et al. J. Am. Chem. Soc. 106, 731 (1984); Edwards, M.P., et al. J. Org. Chem. 49, 3503 (1984); Kelly, A.G., and Roberts, J.S. J. Chem. Soc., Chem. Commun. 228, (1980); Ogawa, T., et al. Carbohydr. Res. 57, C31 (1977); Isobe, M., et al. Tetrahedron Lett. 28, 6485 (1987); Fresnos, J.N. and Swenton, J.S. , J. Chem. Soc., Chem. Commun. 658, (1985); Kochetkov, N.K. et al., Tetrahedron Lett. 22, 4315, 4319 (1981); Georges, M. et al., Carbohydr. Res. 130, 115 (1984); Paulsen, et al., Chem. Ber. 114, 322 (1981).

Fórmula: C₆H₁₀O₅

Cor e Forma: Neat

Peso molecular: 162.14

Ref: TR-A648100

1,6-Anhydro-beta-D-glucopyranose

CAS: 498-07-7

Used for preparation of biologically active compounds

Fórmula: C₆H₁₀O₅

Pureza: Min. 98 Area-%

Cor e Forma: White Powder

Peso molecular: 162.14 g/mol

Ref: 3D-ML06636

1,6-Anhydro-β-d-glucose

CAS: 498-07-7

Fórmula: C₆H₁₀O₅

Pureza: 95%

Cor e Forma: Solid, Light beige powder

Peso molecular: 162.053

Ref: 10-F046709