CAS 101-68-8

Benzene, 1,1'-methylenebis[4-isocyanato-

Description:

The chemical substance known as Benzene, 1,1'-methylenebis[4-isocyanato-], commonly referred to as MDI (Methylene Diphenyl Diisocyanate), is an aromatic isocyanate used primarily in the production of polyurethane foams and coatings. It is characterized by its high reactivity due to the presence of isocyanate functional groups, which readily react with compounds containing active hydrogen atoms, such as alcohols and amines. MDI is typically a viscous liquid or solid at room temperature, with a distinct aromatic odor. It is insoluble in water but soluble in organic solvents like acetone and toluene. MDI is known for its excellent thermal stability and mechanical properties, making it suitable for various industrial applications, including insulation materials and elastomers. However, it is also associated with health risks, as exposure can lead to respiratory issues and skin sensitization, necessitating proper handling and safety precautions in industrial settings.

Formula: C₁₅H₁₀N₂O₂

InChI: InChI=1/C15H10N2O2/c18-10-16-14-5-1-12(2-6-14)9-13-3-7-15(8-4-13)17-11-19/h1-8H,9H2

InChI key: InChIKey=UPMLOUAZCHDJJD-UHFFFAOYSA-N

SMILES: C(C1=CC=C(N=C=O)C=C1)C2=CC=C(N=C=O)C=C2

Synonyms:

• 1,1'-Methylenebis[4-isocyanatobenzene]
• 4,4'-Bis(isocyanatophenyl)methane
• 4,4'-Diisocyanatodiphenylmethane
• 4,4'-Diphenylmethane diisocyanate
• 4,4'-Diphenylmethane diisocyanate (MDI)
• 4,4'-Mdi
• 4,4'-Methylendiphenyldiisocyanat
• 4,4'-Methylenebis(isocyanatobenzene)
• 4,4'-Methylenebis(phenyl isocyanate)
• 4,4'-Methylenedi(phenyl isocyanate)
• 4,4'-Methylenedi-p-phenylene diisocyanate
• 4,4'-Methylenediphenyl Diisocyanate
• 4,4'-Methylenediphenyldiisocyanate
• 4,4'-Methylenediphenylene isocyanate
• 4,4′-Methylenebis(phenylisocyanate)
• Benzene, 1,1'-methylenebis[4-isocyanto-
• Bis (4-isocyanatophenyl)metan
• Bis(1,4-isocyanatophenyl)methane
• Bis(4-Isocyanatophenyl)Methane
• Bis(4-isocianatofenil)metano
• Bis(4-isocianatofenile)metano
• Bis(Phenylisocyanate), 4,4'-Methylene-
• Bis(isocyanatophenyl)methane
• Bis(p-isocyanatophenyl)methane
• Bis-(4-Isocyanatophenyl)methan
• Bis[1-Isocyanatobenzene], 4,4'-Methylene-
• Ddifenilmetano Diisocianato (MDI)
• Di(4-isocyanatophenyl)methane
• Di-isocyanate de diphénylméthane (MDI)
• Diisocianato De 4,4'-Metilendifenilo
• Diisocianato de difenilmetano (MDI)
• Diisocyanate De 4,4'-Methylenediphenyle
• Diisocyanatodiphenylmethane
• Diphenyl Methanediisocyanate
• Diphenyl methane diisocyanate
• Diphenylmetan diisocyanat (MDI)
• Diphenylmethan-4,4'-Diisocyanat
• Diphenylmethandiisocyant (MDI)
• Diphenylmethane 4,4'-diisocyanate
• Diphenylmethane diisocyanate
• Diphenylmethane diisocyanate (MDI)
• Diphenylmethane-4.4'-diisocyanate
• Diphenylmethyl Diisocyanate
• Diphenylmethylene 4,4′-diisocyanate
• Diphenylmethylene diisocyanate
• Isocyanic acid, diphenylmethylene ester
• Isocyanic acid, methylenedi-p-phenylene ester
• MDI
• Mdi 80
• Methylbiphenyl isocyanat
• Methylbis(4-phenylisocyanate)
• Methyldi-p-phenylene isocyanate
• Methylenbisphenylisocyanat
• Methylene Bisphenyl Isocyanate
• Methylene diisocyanate
• Methylene diphenyl diisocyanate
• Methylene-Diphenylene Di-Isocyanate (M.D.I.)
• Methylenebis(4-isocyanatobenzene)
• Methylenebis(4-phenyl isocyanate)
• Methylenebis(4-phenylene isocyanate)
• Methylenebis(p-phenyl isocyanate)
• Methylenebis(p-phenylene isocyanate)
• Methylenebis(phenyl isocyanate)
• Methylenebis(phenylisocyanate)
• Methylenebis(phenylisocyanate) (MDI)
• Methylenebis-p-phenylene diisocyanate
• Methylenebisphenylene diisocyanate
• Methylenebisphenylene diisocyanate, 4,4'-
• Methylenedi-p-phenylene diisocyanate
• Methylenedi-p-phenylene isocyanate
• Methylenediphenylisocyanate
• Metilene Bisfenil Isocianato
• Méthylène biphényl isocyanate
• Monomeric 4,4'-methylenediphenyl diisocyanate aerosol
• Nsc 9596
• P,P'-Methylenebis(Phenyl Isocyanate)
• Phenylmethane diisocyanate
• YHM
• p,p'-Diphenylmethane diisocyanate
• p,p′-Methylene diphenyl diisocyanate
• p,p′-Methylenediphenyl diisocyanate
• desmodur 44
• isonate 125m
• isonate 125mf
• nocconate 300
• 4,4'-Methylene bisphenyl isocyanate
• 1,1'-methanediylbis(4-isocyanatobenzene)
• Methylene diphenyl diisocyanate (monomeric and pol? METHYLENE BISPHENYL ISOCYANATE
• Methylenedi-p-phenyl diisocyanate, stabilized flakes, contains 1.5% 2,4[-isomer
• Methylenedi-p-phenyl diisocyanate
• caradate 30
• 4,4'-methylenedi(4,1-phenylene) isocyanate
• 4,4'-diphenyl methane diisocyanate
• Benzene, 1,1′-methylenebis[4-isocyanato-
• hylene m50
• VANCHEM HM-50
• Diphenyl methene-4，4′diisocyanate
• METHYLENEDIPHENYLENE DIISOCYANATE
• VANCHEM HM-4346
• DIPHENYLMETHAN-4,4'-DIISOCYANATE
• METHYLENEDIPHENYL 4,4'-DIISOCYANATE
• 1,1’-methylenebis(4-isocyanato)-benzene
• METHYLENE DI-P-PHENYLENE DIISOCYANATE

Methylenediphenyl 4,4'-Diisocyanate

CAS: 101-68-8

Formula: C₁₅H₁₀N₂O₂

Purity: >97.0%(T)

Color and Shape: White to Almost white powder to lump

Molecular weight: 250.26

Ref: 3B-D0897

4,4'-Methylenebis(phenyl isocyanate), 98%

CAS: 101-68-8

4,4'-Methylenebis(phenyl isocyanate) acts as a monomer in the production of polyurethane. The rigid polyurethane foams are good thermal insulators, which find applications in all freezers and refrigerators, as well as in buildings. It is also used as an industrial strength adhesive, which is availab

Formula: C₁₅H₁₀N₂O₂

Purity: 98%

Color and Shape: White to yellow, Crystals or powder or crystalline powder or flakes or fused solid

Molecular weight: 250.26

Ref: 02-L15740

1,1'-Methanediylbis(4-isocyanatobenzene)

CAS: 101-68-8

1,1'-Methanediylbis(4-isocyanatobenzene)

Purity: 98%

Color and Shape: White To Off White Solid

Molecular weight: 250.25g/mol

Ref: 54-OR1573

Diphenylmethan-4,4'-diisocyanate

Controlled Product

CAS: 101-68-8

Formula: C₁₅H₁₀N₂O₂

Color and Shape: Neat

Molecular weight: 250.25

Ref: 04-CA12905000

4,​4'-​Methylenebis(phenyl Isocyanate)

Controlled Product

CAS: 101-68-8

Applications 4,​4'-​Methylenebis(phenyl Isocyanate) is used in the manufacture of bio-based polyurethanes and resins used in flame retardants.Environmental toxin on US EPA Toxic Release Inventory list (TRI) list.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Feng, Y. et al.: ACS Sust. Chem. Eng., 5, 7365 (2017); Yan, H. et al.: Ind. Eng. Chem. Res., 56, 8408 (2017);

Formula: C₁₅H₁₀N₂O₂

Color and Shape: White

Molecular weight: 250.25

Ref: TR-M227380

4,4′-Diphenylmethanediisocyanate

CAS: 101-68-8

Formula: C₁₅H₁₀N₂O₂

Purity: 97.0%

Color and Shape: Solid, Crystalline Powder or Solid or Lumps or Flakes

Molecular weight: 250.257

Ref: 10-F136500

Methylenedi-p-phenyl diisocyanate

CAS: 101-68-8

Methylenedi-p-phenyl diisocyanate (MDI) is a glycol ether, which is a potent inducer of allergic reactions. It can be found in polyurethane foam insulation and in the production of diphenyl and diisocyanate. MDI has been shown to cause asthma, skin inflammation, and other respiratory problems. MDI is highly toxic to aquatic life and can cause long term effects on fish populations. The toxicity of MDI depends on the concentration and duration of exposure, as well as the species that it is administered to. High concentration exposure for a short period of time will result in death by respiratory failure or cardiac arrest. Longer exposure at lower concentrations may lead to liver, kidney, lung damage or cancerous tumor development.

Formula: C₁₅H₁₀N₂O₂

Purity: Min. 95%

Molecular weight: 250.25 g/mol

Ref: 3D-FM37903