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CAS 102525-11-1

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1,5-CYCLOOCTADIENE(H5-INDENYL)IRIDIUM (I)

Description:
1,5-Cyclooctadiene (H5-Indenyl)iridium (I) is a coordination compound featuring iridium as the central metal atom, coordinated with a cyclooctadiene ligand and an indenyl group. This compound is characterized by its unique structure, which includes a cyclic diene that can participate in various chemical reactions, particularly in catalysis. The iridium center typically exhibits a low oxidation state, which is crucial for its reactivity in catalytic processes, such as olefin hydrogenation and C–C coupling reactions. The presence of the indenyl ligand enhances the stability and reactivity of the complex, making it a valuable precursor in organic synthesis and materials science. Additionally, this compound may exhibit interesting electronic properties due to the d-orbital characteristics of iridium, which can influence its behavior in catalytic cycles. Its applications are often explored in the context of organometallic chemistry, where it serves as a catalyst or catalyst precursor in various organic transformations. Safety and handling precautions should be observed due to the potential toxicity associated with iridium compounds.
Formula:C17H19Ir
InChI:InChI=1/C9H7.C8H12.Ir/c1-2-5-9-7-3-6-8(9)4-1;1-2-4-6-8-7-5-3-1;/h1-7H;1-2,7-8H,3-6H2;/b;2-1-,8-7-;
SMILES:c1ccc2[CH]C=Cc2c1.C1=CCCC=CCC1.[Ir]
Synonyms:
  • (1,5-Cyclooctadiene)(Eta5-Indenyl)Irid&
  • 1,5-Cyclooctadiene(h5-indenyl)iridium(I),99%
  • (1,5-Cyclooctadiene)-η:5-indenyl)iridium(I)
  • 1H-indene-1,2,3,3a,7a-pentayl, 2,3-dihydro-, compd. with (1Z,5Z)-1,5-cyclooctadiene, iridium salt (1:1:1)
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