CAS 104322-63-6

(1S)-(+)-(Camphorylsulfonyl)oxaziridine

Description:

(1S)-(+)-(Camphorylsulfonyl)oxaziridine is a chiral oxaziridine compound characterized by its unique structural features, which include a camphor-derived sulfonyl group. This compound is notable for its use in asymmetric synthesis, particularly in the formation of enantiomerically enriched amines through oxidation reactions. The presence of the oxaziridine ring contributes to its reactivity, allowing it to act as a powerful electrophile in various chemical transformations. The camphor moiety imparts steric hindrance and influences the selectivity of reactions, making it valuable in the field of organocatalysis and synthetic organic chemistry. Additionally, the compound's chirality is significant for applications in pharmaceuticals, where the specific enantiomer can exhibit different biological activities. Its stability and reactivity profile make it a useful intermediate in the synthesis of complex molecules. Overall, (1S)-(+)-(Camphorylsulfonyl)oxaziridine exemplifies the intersection of structural complexity and functional utility in modern organic synthesis.

Formula: C₁₀H₁₅NO₃S

InChI: InChI=1/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9+,10+,11?/m1/s1

Synonyms:

• (+)-(2R,8As)-(Camphorylsulfonyl)Oxaziridine
• (1S)-(+)-2,N-Epoxy-Exo-10,2-Bornanesultam
• (1S)-(+)-(10-Camphorsulfonyl)Oxaziridine
• (1S)-(+)-(10-Camphorsulphonyl)Oxaziridine
• (+)-((Camphoryl)Sulfonyl)Oxaziridine
• (S)-(+)-(Camphorsulfonyl)Oxaziridine
• 9,9-Dimethyltetrahydro-4A,7-Methanooxazireno[3,2-I][2,1]Benzothiazole 3,3-Dioxide
• (4aR,7S,8aS)-9,9-dimethyltetrahydro-4a,7-methanooxazireno[3,2-i][2,1]benzisothiazole 3,3-dioxide
• (4aS,7R,8aS)-9,9-dimethyltetrahydro-4a,7-methanooxazireno[3,2-i][2,1]benzisothiazole 3,3-dioxide
• (+)-Camphorsulfonyloxaziridine

(2R,8aS)-(+)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]

CAS: 104322-63-6

Formula: C₁₀H₁₅NO₃S

Purity: >95.0%(T)

Color and Shape: White to Almost white powder to crystal

Molecular weight: 229.29

Ref: 3B-C1326

(1S)-(+)-(10-Camphorsulfonyl)oxaziridine

CAS: 104322-63-6

Formula: C₁₀H₁₅NO₃S

Purity: 97%

Color and Shape: Solid

Molecular weight: 229.2960

Ref: IN-DA003BHW

(1S)-(+)-(10-Camphorsulphonyl)oxaziridine

CAS: 104322-63-6

(1S)-(+)-(10-Camphorsulphonyl)oxaziridine

Formula: C₁₀H₁₅NO₃S

Purity: 95%

Color and Shape: white solid

Molecular weight: 229.30g/mol

Ref: 54-OR55115

(1S)-(+)-(10-Camphorsulfonyl)oxaziridine

CAS: 104322-63-6

(1S)-(+)-(10-Camphorsulfonyl)oxaziridine is a chemical compound that is used as a reagent in organic synthesis. It can be used as a building block for the construction of more complex compounds. This chemical has been shown to react with cyclic amines, such as pyrrolidine and piperidine, to form oxazolidines. The reaction of (1S)-(+)-(10-camphorsulfonyl)oxaziridine with acetyl chloride forms the corresponding sulfonyl chloride, which can be further reacted with an amine to produce 4-amino-N-(2-hydroxyethyl)benzenesulfonamide.

Formula: C₁₀H₁₅NO₃S

Purity: Min. 95 Area-%

Color and Shape: White Powder

Molecular weight: 229.3 g/mol

Ref: 3D-FC19657

(4aS,7R,8aS)-9,9-Dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide

CAS: 104322-63-6

Formula: C₁₀H₁₅NO₃S

Purity: 95%

Color and Shape: Solid, Crystalline

Molecular weight: 229.29

Ref: 10-F317939

(1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Controlled Product

CAS: 104322-63-6

Applications A useful synthetic intermediate. Used for asymmetric hydroxylation.
References Davis, F.A., et al.: J. Am. Chem. Soc., 112, 6679 (1990)

Formula: C₁₀H₁₅NO₃S

Color and Shape: White Powder

Molecular weight: 229.30

Ref: TR-C175100