CAS 104372-31-8

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Description:

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a chiral oxaziridine compound characterized by its unique structure, which includes a five-membered ring containing nitrogen and oxygen atoms. This compound is derived from camphorsulfonic acid, contributing to its distinctive properties. It is typically used as a reagent in organic synthesis, particularly in asymmetric oxidation reactions, due to its ability to facilitate the introduction of oxygen into organic substrates. The presence of the camphor moiety imparts significant steric hindrance, enhancing its selectivity in reactions. Additionally, the oxaziridine ring is known for its reactivity, allowing it to participate in various chemical transformations. The compound is generally stable under standard conditions but may require careful handling due to its potential reactivity. Its chiral nature makes it valuable in the synthesis of enantiomerically pure compounds, which is crucial in pharmaceuticals and agrochemicals. Overall, (1R)-(-)-(10-Camphorsulfonyl)oxaziridine is an important tool in the field of synthetic organic chemistry.

Formula: C₁₁H₁₇NO₄S

InChI: InChI=1/C11H17NO4S/c1-10(2)8-3-4-11(10,9(13)5-8)6-17(14,15)12-7-16-12/h8H,3-7H2,1-2H3

InChI key: InChIKey=GBBJBUGPGFNISJ-SKVWKECBSA-N

SMILES: CC1(C)C2CCC1(CS(=O)(=O)N1CO1)C(=O)C2

Synonyms:

• (-)-((Camphoryl) Sulfonyl)Oxaziridine
• (-)-(2S,8Ar)-(Camphorsulfonyl)Oxaziridine
• (-)-(Camphorsulfonyl)oxaziridine
• (-)-(Camphorylsulfonyl)oxaziridine
• (-)-Camphorsulfonyloxaziridine
• (1R)-(-)-(10-Camphorsulphonyl)Oxaziridine
• (1R)-(-)-(Camphorylsulfonyl)Oxaziridine
• (1R)-(-)-2,N-Epoxy-Exo-10,2-Bornanesultam
• (2S,8Ar)-(-)-(Camphorylsulfonyl)Oxaziridine
• (R)-2,N-Epoxy-Exo-10,2-Bornanesultam
• 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole, tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aR,7S,8aR)-
• 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole, tetrahydro-9,9-dimethyl-, 3,3-dioxide, [4aR-(4aα,7α,8aR*)]-
• 7,7-Dimethyl-1-[(Oxaziridin-2-Ylsulfonyl)Methyl]Bicyclo[2.2.1]Heptan-2-One

(2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]

CAS: 104372-31-8

Formula: C₁₀H₁₅NO₃S

Purity: >95.0%(T)

Color and Shape: White to Almost white powder to crystal

Molecular weight: 229.29

Ref: 3B-C1327

(1R,2S)-(-)-2,N-Epoxy-10,2-camphorsultam, 96%

CAS: 104372-31-8

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Sci

Formula: C₁₀H₁₅NO₃S

Purity: 96%

Color and Shape: White to pale cream, Crystalline powder or powder

Molecular weight: 229.29

Ref: 02-H59544

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

CAS: 104372-31-8

Formula: C₁₀H₁₅NO₃S

Purity: 98%

Color and Shape: Solid

Molecular weight: 229.2960

Ref: IN-DA007HY1

(1R)-(-)-(10-Camphorsulfonyl)Oxaziridine

CAS: 104372-31-8

(1R)-(-)-(10-Camphorsulfonyl)Oxaziridine

Purity: 98%

Molecular weight: 229.30g/mol

Ref: 54-OR1007862

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

CAS: 104372-31-8

Formula: C₁₀H₁₅NO₃S

Purity: 95%

Color and Shape: Solid

Molecular weight: 229.29

Ref: 10-F471538

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Controlled Product

CAS: 104372-31-8

Applications A useful synthetic intermediate. Used for asymmetric hydroxylation.
References Davis, F.A., et al.: J. Am. Chem. Soc., 112, 6679 (1990)

Formula: C₁₀H₁₅NO₃S

Color and Shape: Neat

Molecular weight: 229.30

Ref: TR-C175095