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CAS 105029-70-7

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Tetra-N-Butylphosphonium Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)Nickel(Iii) Complex

Description:
Tetra-N-Butylphosphonium Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)Nickel(III) Complex, with the CAS number 105029-70-7, is a coordination compound featuring a nickel center coordinated by dithiolene ligands. This complex typically exhibits a distinctive deep color, often associated with its electronic transitions, which can be attributed to the presence of the nickel(III) oxidation state. The tetra-n-butylphosphonium cation serves as a stabilizing counterion, enhancing the solubility of the complex in organic solvents. The dithiolene ligands contribute to the complex's electronic properties, allowing for potential applications in fields such as organic electronics and catalysis. The compound is characterized by its stability under ambient conditions, although it may be sensitive to light and moisture. Its synthesis often involves the reaction of nickel salts with dithiolene precursors in the presence of the phosphonium salt. Overall, this complex represents a fascinating intersection of coordination chemistry and materials science, with potential implications in various technological applications.
Formula:C22H36NiPS10
InChI:InChI=1/C16H36P.2C3H2S5.Ni/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*4-1-2(5)8-3(6)7-1;/h5-16H2,1-4H3;2*4-5H;/q+1;;;+3/p-4/rC16H36P.C6NiS10/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;8-5-10-1-2(11-5)15-7(14-1)16-3-4(17-7)13-6(9)12-3/h5-16H2,1-4H3;/q+1;-1
Synonyms:
  • Tetra-N-Butylphosphonium Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)- Nickel(3) Complex
  • Tetrabutylphosphonium Bis(4,5-Dimercapto-1,3-Dithiol-2-Thionato-S4,S5)Niccolate(Iii)
  • Tetrabutylphosphonium Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)Nickel(Iii) Complex
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