CAS 106681-15-6: Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

Description: Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) is a coordination complex featuring ruthenium as the central metal ion, coordinated to a chiral ligand derived from binaphthyl and diphosphine groups. This compound is characterized by its bidentate coordination through the phosphine ligands, which enhances its stability and reactivity. The presence of the diacetato groups contributes to its solubility and potential reactivity in various chemical environments. The chiral nature of the ligand imparts stereochemical properties, making it useful in asymmetric catalysis, particularly in reactions such as hydrogenation and cross-coupling. The compound is typically characterized by its distinct UV-Vis and NMR spectroscopic signatures, which reflect the electronic environment around the ruthenium center and the phosphine ligands. Additionally, its catalytic properties can be influenced by the steric and electronic effects of the p-tolyl substituents on the phosphine groups. Overall, this complex is significant in the field of organometallic chemistry and catalysis, particularly for its applications in synthesizing chiral compounds.

Formula: C₅₂H₄₆O₄P₂Ru

Synonyms:

• (S)-Ru(OAc)2(T-BINAP)

Ru(OAc)2[(S)-tolbinap]

CAS: 106681-15-6

• Formula: C₅₂H₄₆O₄P₂Ru
• Color and Shape: Yellow to Brown to Dark green powder to crystal
• Molecular weight: 897.95

Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)₂[(S)-tolbinap]

CAS: 106681-15-6

Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]

• Formula: C₅₂H₄₆O₄P₂Ru
• Color and Shape: brown pwdr.
• Molecular weight: 897.94

(S)-Ru(OAc)2(T-BINAP)

CAS: 106681-15-6

• Formula: C₅₂H₄₈O₄P₂Ru
• Purity: 95%
• Color and Shape: Solid
• Molecular weight: 899.9526

Ru(Oac)2[(S)-Tolbinap]

CAS: 106681-15-6

• Purity: 98%
• Molecular weight: 897.94g/mol

(S)-Ru(OAc)2(T-binap)

CAS: 106681-15-6

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• Formula: C₅₂H₄₆O₄P₂Ru
• Purity: Min. 95%
• Molecular weight: 897.94 g/mol