CAS 1070-89-9: Sodium bis(trimethylsilyl)amide

Description:Sodium bis(trimethylsilyl)amide, commonly referred to as NaHM(SiMe3)2, is an organosilicon compound characterized by its strong basicity and nucleophilicity. It is typically encountered as a white to light yellow solid and is highly soluble in non-polar solvents such as hexane and toluene, but insoluble in polar solvents like water. The compound features a sodium cation and a bis(trimethylsilyl)amide anion, which contributes to its reactivity, particularly in deprotonation reactions. Sodium bis(trimethylsilyl)amide is often used as a reagent in organic synthesis, particularly in the formation of carbon-nitrogen bonds and as a strong base in various chemical transformations. It is sensitive to moisture and air, requiring careful handling and storage under inert atmospheres to prevent hydrolysis and degradation. Due to its reactivity, it is important to use appropriate safety measures when working with this compound, as it can react vigorously with water and other protic solvents, releasing trimethylsilanol and potentially hazardous byproducts.

Formula:C₆H₁₉NSi₂·Na

InChI:InChI=1S/C6H19NSi2.Na/c1-8(2,3)7-9(4,5)6;/h7H,1-6H3;

InChI key:InChIKey=QKNDAUTYSODFJV-UHFFFAOYSA-N

SMILES:[Na].N([Si](C)(C)C)[Si](C)(C)C

Synonyms:
1,1,1,3,3,3-Hexamethyldisilazane sodium salt
1,1,1-trimethyl-N-(trimethylsilyl)silanamine
Bis(trimethylsilyl)amine sodium salt
Disilazane, 1,1,1,3,3,3-hexamethyl-, sodium deriv.
Hexamethyldisilazane sodium salt
Hexamethyldisilazylsodium
N,N-Bis(trimethylsilyl)amine sodium salt
NaHMDS
NaMDS
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, sodium salt
See more synonyms
Sodiobis(trimethylsilyl)amine
Sodium 1,1,1,3,3,3-Hexamethyldisilazan-2-Ide
Sodium Hexamethyldisilazide
Sodium N,N-bis(trimethylsilyl)amide
Sodium bis(trimethylsilyl)amide
Sodium bis(trimethylsilyl)amide(1-)
Sodium bis(trimethylsilyl)amine
Sodium hexamethyldisilazane
Sodium hexamethyldisilylamide
Sodium, [bis(trimethylsilyl)amino]-
silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, sodium salt (1:1)

Found 17 products.

Product data	Purity	Price range	Estimated delivery
Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L) REF: 3B-H0894CAS: 1070-89-9	- - -	163.00 €~589.00 €	Fri 25 Apr 25
Sodium bis(trimethylsilyl)amide 1M in THF REF: 10-S14981CAS: 1070-89-9	- - -	88.00 €	Fri 25 Apr 25
Sodium bis(trimethylsilyl)amide, 2M soln. in THF REF: 02-L13352CAS: 1070-89-9	- - -	To inquire	Mon 28 Apr 25
Sodium bis(trimethylsilyl)amide, 1M soln. in THF REF: 02-L08779CAS: 1070-89-9	- - -	90.00 €~265.00 €	Mon 28 Apr 25
Sodium hexamethyldisilazane, min. 95% REF: 08-11-1500CAS: 1070-89-9	min. 95%	53.00 €~196.00 €	Tue 29 Apr 25
Sodium bis(trimethylsilyl)amide 2M in THF REF: 10-S14980CAS: 1070-89-9	- - -	30.00 €~176.00 €	Mon 28 Apr 25
Sodium bis(trimethylsilyl)amide REF: IN-DA0035LDCAS: 1070-89-9	95%	To inquire	Fri 02 May 25
Sodium bis(trimethylsilyl)amide, 2M in THF REF: 54-OR33650CAS: 1070-89-9	Molarity: 2.02m (Typical Value in Batch COA)	145.00 €~398.00 €	Mon 05 May 25
Sodium bis(trimethylsilyl)amide, pure, 2M solution in THF, AcroSeal™ REF: AC-27785CAS: 1070-89-9 109-99-9	- - -	106.00 €~527.00 €	Mon 05 May 25
Sodium bis(trimethylsilyl)amide, 95+%, pure REF: AC-21596CAS: 1070-89-9	95+%	59.00 €~500.00 €	Mon 05 May 25
Sodium bis(trimethylsilyl)amide (95%) REF: TR-S614653CAS: 1070-89-9	95%	92.00 €~208.00 €	Wed 21 May 25
CALLERY™ Sodium hexamethyldisilazane, 40% solution in tetrahydrofuran REF: 08-11-1275CAS: 1070-89-9	- - -	93.00 €~832.00 €	Tue 27 May 25
Sodium bis(trimethylsilyl)amide REF: 3D-FS162456CAS: 1070-89-9	Min. 95%	To inquire	Fri 13 Jun 25
Sodium bis(trimethylsilyl)amide, 98% REF: 02-033505CAS: 1070-89-9	98%	- - -	Discontinued product
Sodium bis(trimethylsilyl)amide, 1M in THF solution REF: 3D-FS184293CAS: 1070-89-9	Min. 95%	- - -	Discontinued product
SODIUM BIS(TRIMETHYLSILYL)AMIDE, 95% REF: 3H-SIS6980.0CAS: 1070-89-9	95%	- - -	Discontinued product
Sodium bis(trimethylsilyl)amide - 2M in THF REF: 3D-FS46008CAS: 1070-89-9	Min. 95%	- - -	Discontinued product