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CAS 11136-36-0

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Bis(Pentamethylcyclopentadienyl)titanium dichloride

Description:
Bis(Pentamethylcyclopentadienyl)titanium dichloride, with the CAS number 11136-36-0, is a coordination compound featuring titanium in a low oxidation state, typically +2. This compound is characterized by its unique structure, where two pentamethylcyclopentadienyl ligands are coordinated to a titanium center, along with two chloride ions. The pentamethylcyclopentadienyl ligands contribute to the compound's stability and solubility, often enhancing its reactivity in various chemical processes. It is generally a solid at room temperature and exhibits a distinctive color, which can vary depending on its environment. This compound is of interest in organometallic chemistry and catalysis, particularly in polymerization reactions and as a precursor for titanium-based materials. Its reactivity can be influenced by the steric and electronic properties of the ligands, making it a valuable subject of study in synthetic chemistry. Safety precautions should be observed when handling this compound, as it may pose health risks if ingested or inhaled.
Formula:C20H30Cl2Ti
InChI:InChI=1S/2C10H15.2ClH.Ti/c2*1-6-7(2)9(4)10(5)8(6)3;;;/h2*1-5H3;2*1H;/q2*-1;;;+4/p-2
InChI key:InChIKey=LFMFRUBOWDXPAI-UHFFFAOYSA-L
SMILES:[Cl-][Ti+4]12345678([Cl-])(C=9(C)C1(C)=C2(C)[C-]3(C)C49C)[C-]%10(C)C5(C)=C6(C)C7(C)=C8%10C
Synonyms:
  • 1,2,3,4,5-Pentamethylcyclopenta-1,3-Diene - Dichlorotitanium (2:1)
  • 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, titanium complex
  • Bis(η<sup>5</sup>-pentamethylcyclopentadienyl)titanium dichloride
  • Decamethyltitanocene dichloride
  • Dichlorobis(pentamethylcyclopentadienyl)titanium
  • Dichlorobis(η<sup>5</sup>-pentamethylcyclopentadienyl)titanium
  • Dichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]titanium
  • Permethyltitanocene dichloride
  • Titanium, dichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-
  • Dichlorobis(η5-pentamethylcyclopentadienyl)titanium
  • Bis(pentaMethylcyclopentadienyl) Titanium Dichloride
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