CAS 114615-82-6

TPAP

Description:

TPAP, or tetrapropylammonium perruthenate, is a chemical compound commonly used as a catalyst in organic synthesis, particularly in oxidation reactions. It is characterized by its ability to facilitate the conversion of alcohols to carbonyl compounds, such as aldehydes and ketones, under mild conditions. TPAP is a soluble salt, typically appearing as a dark-colored solid or powder, and is known for its stability and effectiveness in various solvent systems. The compound is often utilized in combination with co-oxidants, such as N-methylmorpholine N-oxide, to enhance its catalytic activity. Due to its specific reactivity and selectivity, TPAP has gained popularity in synthetic organic chemistry, especially in the synthesis of complex molecules. Safety considerations should be taken into account when handling TPAP, as it may pose health risks if ingested or inhaled, and appropriate protective measures should be employed. Overall, TPAP is a valuable reagent in the field of organic synthesis, contributing to efficient and selective chemical transformations.

Formula: C₁₂H₂₈N·O₄Ru

InChI: InChI=1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;;-1

InChI key: InChIKey=WRYCQGLOOXHZLU-UHFFFAOYSA-N

SMILES: [Ru-](=O)(=O)(=O)=O.[N+](CCC)(CCC)(CCC)CCC

Synonyms:

• 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-)
• 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-) (1:1)
• Oxido-Trioxo-Ruthenium
• Ruthenate (RuO₄^1-), (T-4)-, N,N,N-tripropyl-1-propanaminium
• Tetra-n-propylammonium perruthenate
• Tetrapropylammonium
• Tetrapropylammonium perruthenate
• Tetrapropylammonium perruthenate(1-)
• Tetrapropylammonium tetraoxoruthenate
• Tetrapropylammonium tetraoxoruthenate(1-)
• Tpap

Tetrapropylammonium Perruthenate

CAS: 114615-82-6

Formula: C₁₂H₂₈NO₄Ru

Color and Shape: Dark green to Dark blue to Black powder to crystal

Molecular weight: 351.43

Ref: 3B-T1559

Tetra-n-propylammonium perruthenate(VII), 98%

CAS: 114615-82-6

Tetra-n-propylammonium perruthenate a catalytic oxidant used in conjunction with N-methylmorpholine N-oxide for oxidation of primary secondary alcohols to aldehydes and ketones.This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation

Formula: C₁₂H₃₆NO₄Ru

Purity: 98%

Color and Shape: powder, Black

Molecular weight: 359.49

Ref: 02-B24511

Tetrapropylammonium perruthenate, min. 97% TPAP

CAS: 114615-82-6

Tetrapropylammonium perruthenate, min. 97% TPAP

Formula: (C₃H₇)₄NRuO₄

Purity: min. 97%

Color and Shape: green xtl.

Molecular weight: 351.43

Ref: 08-44-7850

1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-) (1:1)

CAS: 114615-82-6

Formula: C₁₂H₂₈NO₄Ru

Purity: 97%

Color and Shape: Solid

Molecular weight: 351.4250

Ref: IN-DA000ETO

Tetrapropylammonium perruthenate

CAS: 114615-82-6

Tetrapropylammonium perruthenate

Formula: ·C₁₂H₂₈N·O₄Ru

Purity: 98%

Color and Shape: black solid

Molecular weight: 351.42502g/mol

Ref: 54-OR52342

Tetrapropylammonium perruthenate

CAS: 114615-82-6

Formula: C₁₂H₂₈NO₄Ru

Purity: 98%

Color and Shape: Solid, Dark green solid

Molecular weight: 351.43

Ref: 10-F241264

Tetrapropylammonium Perruthenate

Controlled Product

CAS: 114615-82-6

Applications Tetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.
References Lybaert, J. et al.: Electrochim. Acta., 182, 693 (2015);

Formula: C₁₂H₂₈NO₄Ru

Color and Shape: Neat

Molecular weight: 351.43

Ref: TR-T310610

Tetrapropylammonium perruthenate

CAS: 114615-82-6

Tetrapropylammonium perruthenate is a polymeric matrix that contains a chelate ligand and can be used as an oxygen sensor. The polymer is synthesized in the presence of trifluoroacetic acid (TFA) using tetrapropylammonium chloride (TPACl) and perruthenate. Tetrapropylammonium perruthenate forms a polymeric matrix with TPACl, which contains a chelate ligand. The polymer is sensitive to changes in the environment such as pH, temperature, and oxidation-reduction potential. The polymeric matrix can be used for sensing the concentration of oxygen in liquid or gas phase by measuring fluorescence intensity at various wavelengths. These measurements are correlated with the concentration of oxygen in the environment.

Formula: C₁₂H₂₈NO₄Ru

Purity: Min. 95%

Molecular weight: 351.43 g/mol

Ref: 3D-FT60357