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CAS 12081-16-2

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Di-μ-chlorotetrakis(η2-ethene)dirhodium

Description:
Di-μ-chlorotetrakis(η²-ethene)dirhodium, with the CAS number 12081-16-2, is a coordination compound featuring a rhodium metal center coordinated by ethene ligands and chloride ions. This compound is characterized by its unique structure, where two rhodium atoms are bridged by two chloride ions (μ-chloride), and each rhodium is further coordinated to multiple ethene molecules in a bidentate fashion (η²). The presence of ethene ligands contributes to its reactivity and potential applications in catalysis, particularly in organic transformations such as olefin metathesis and hydroformylation. The compound typically exhibits a distinctive color, which can vary depending on its environment and the presence of other ligands. Its stability and reactivity can be influenced by factors such as temperature, solvent, and the presence of other coordinating species. Overall, Di-μ-chlorotetrakis(η²-ethene)dirhodium is an important compound in organometallic chemistry, showcasing the interplay between metal coordination and organic ligand behavior.
Formula:C8H16Cl2Rh2
InChI:InChI=1S/4C2H4.2ClH.2Rh/c4*1-2;;;;/h4*1-2H2;2*1H;;/q;;;;;;2*+1/p-2
InChI key:InChIKey=OOQJCPOXJFCGCR-UHFFFAOYSA-L
SMILES:[Rh+]123([Cl-][Rh+]45([Cl-]1)([CH2]=[CH2]4)[CH2]=[CH2]5)([CH2]=[CH2]2)[CH2]=[CH2]3
Synonyms:
  • Bis((μ-chloro)bis(ethylene)rhodium)
  • Bis(chlorobis(η<sup>2</sup>-ethylene)rhodium)
  • Bis(ethene)rhodium chloride dimer
  • Bis(ethene)rhodium(I) chloride dimer
  • Bis(ethylene)rhodium chloride dimer
  • Bis(ethylene)rhodium(I) chloride dimer
  • Bis(η<sup>2</sup>-ethene)chlororhodium dimer
  • Bis(μ-chloro)tetrakis(ethylene)dirhodium
  • Bis[chlorobis(ethylene)rhodium]
  • Bis[chlorodiethylenerhodium]
  • See more synonyms
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