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CAS 12091-64-4

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Molybdenum, hexacarbonylbis(η5-2,4-cyclopentadien-1-yl)di-, (Mo-Mo)

Description:
Molybdenum hexacarbonylbis(η5-2,4-cyclopentadien-1-yl)di- (Mo-Mo) is a complex organometallic compound characterized by its unique structure and bonding. It features molybdenum in a low oxidation state, coordinated to six carbonyl (CO) ligands and two cyclopentadienyl (Cp) ligands, which are bound in a η5 fashion, indicating that they coordinate through all five carbon atoms. This compound exhibits notable stability due to the strong π-acceptor properties of the carbonyl ligands, which enhance the electron density around the molybdenum centers. The presence of the cyclopentadienyl ligands contributes to the overall stability and solubility of the compound in organic solvents. Molybdenum hexacarbonyl complexes are often used in catalysis and materials science due to their ability to facilitate various chemical reactions. Additionally, the compound's unique electronic properties make it of interest in studies related to organometallic chemistry and coordination chemistry. Safety precautions should be taken when handling this compound, as it may pose health risks due to the toxicity of molybdenum and carbon monoxide.
Formula:C16H10Mo2O6
InChI:InChI=1S/2C5H5.6CO.2Mo/c2*1-2-4-5-3-1;6*1-2;;/h2*1-5H;;;;;;;;/q2*-1;;;;;;;2*+1
InChI key:InChIKey=IBSNOLHYIPMFGP-UHFFFAOYSA-N
SMILES:C(#O)[Mo+]1234(C#O)(C#O)([CH-]5[CH]1=[CH]2[CH]3=[CH]45)[Mo+]6789(C#O)(C#O)(C#O)[CH-]%10[CH]6=[CH]7[CH]8=[CH]9%10
Synonyms:
  • Hexacarbonyldi-π-cyclopentadienyldimolybdenum
  • Molybdenum, hexacarbonyldicyclopentadienyldi-
  • Molybdenum, hexacarbonyldi-π-cyclopentadienyldi-
  • Bis(π-cyclopentadienylmolybdenum tricarbonyl)
  • Molybdenum, hexacarbonylbis(η5-2,4-cyclopentadien-1-yl)di-, (Mo-Mo)
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