CymitQuimica logo

CAS 12129-69-0

:

Tricarbonyl[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]tungsten

Description:
Tricarbonyl[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]tungsten is a coordination complex of tungsten, characterized by its unique structure and properties. This compound features a tungsten center coordinated to three carbonyl (CO) ligands and a trimethylbenzene ligand that binds in a hapticity of six, indicating that it interacts with the metal through all six carbon atoms of the aromatic ring. The presence of carbonyl groups contributes to its stability and reactivity, as these ligands can participate in various chemical reactions, including substitution and insertion processes. The complex is typically characterized by its distinctive infrared (IR) absorption bands corresponding to the carbonyl stretching vibrations. Additionally, it may exhibit interesting electronic properties due to the presence of the aromatic ligand, which can influence the overall electronic environment of the tungsten center. This compound is of interest in organometallic chemistry and catalysis, where it may serve as a precursor or catalyst in various organic transformations.
Formula:C12H12O3W
InChI:InChI=1S/C9H12.3CO.W/c1-7-4-8(2)6-9(3)5-7;3*1-2;/h4-6H,1-3H3;;;;
InChI key:InChIKey=OENLQXWEAUYNBC-UHFFFAOYSA-N
SMILES:C(#O)[W]12345(C#O)(C#O)[CH]=6C1(C)=[CH]2C3(C)=[CH]4C56C
Synonyms:
  • Benzene, 1,3,5-trimethyl-, tungsten complex
  • NSC 120123
  • Tricarbonyl(1,3,5-trimethylbenzene)tungsten
  • Tricarbonyl(mesitylene)tungsten
  • Tricarbonyl(η-mesitylene)tungsten
  • Tricarbonyl(η<sup>6</sup>-1,3,5-trimethylbenzene)tungsten
  • Tricarbonyl(η<sup>6</sup>-mesitylene)tungsten
  • Tricarbonyl[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]tungsten
  • Tungsten, tricarbonyl(mesitylene)-
  • Tungsten, tricarbonyl[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-
  • (Mesitylene)tungsten tricarbonyl
Sort by
Purity (%)
0
100
|
0
|
50
|
90
|
95
|
100
Found 2 products.