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CAS 12148-71-9

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Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium

Description:
Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium, with the CAS number 12148-71-9, is a coordination compound featuring iridium as the central metal atom. This compound is characterized by its unique structure, which includes two iridium centers bridged by methoxy groups and coordinated to cyclooctadiene ligands. The cyclooctadiene ligands are known for their ability to form stable complexes with transition metals due to their π-acceptor properties. The presence of the methoxy groups enhances the solubility and stability of the compound in various solvents. This compound is of interest in organometallic chemistry and catalysis, particularly in reactions involving C-H activation and other transformations. Its unique electronic and steric properties make it a valuable subject of study for understanding metal-ligand interactions and the development of new catalytic systems. Additionally, the compound's reactivity and potential applications in organic synthesis highlight its significance in both academic research and industrial processes.
Formula:C18H30Ir2O2
InChI:InChI=1/2C8H12.2CH3O.4CH3.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;;;;;/h2*1-2,7-8H,3-6H2;2*1H3;4*1H3;;/b2*2-1-,8-7-;;;;;;;;/r2C8H12.C6H18Ir2O2/c2*1-2-4-6-8-7-5-3-1;1-7(2)9(5)8(3,4)10(7)6/h2*1-2,7-8H,3-6H2;1-6H3/b2*2-1-,8-7-;
InChI key:InChIKey=KYTFGRVLJKLCDS-UHFFFAOYSA-N
SMILES:C[O-]1[Ir+]234([O-](C)[Ir+]1567[CH]8=[CH]5CC[CH]6=[CH]7CC8)[CH]9=[CH]2CC[CH]3=[CH]4CC9
Synonyms:
  • (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
  • (1,5-Cyclooctadiene)methoxyiridium dimer
  • (1Z,5Z)-cycloocta-1,5-diene
  • -methoxy)iridium(I) dimer
  • 1,2,2,3,4,4-Hexamethyl-1$L3,3$L3-Dioxa-2$L4,4$L4-Diiridacyclobutane
  • 1,5 Cyclooctadiene(Μ
  • 1,5-Cyclooctadiene, iridium complex
  • Bis((1,5-cyclooctadiene)(μ-methanolato)iridium)
  • Bis(1,5-cyclooctadiene)-di-μ-methoxodiiridium
  • Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium
  • See more synonyms
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