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CAS 12148-72-0

:

Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydirhodium

Description:
Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydirhodium, with the CAS number 12148-72-0, is a coordination compound featuring rhodium as the central metal. This compound is characterized by its unique structure, which includes two methoxy groups bridging two rhodium centers, each coordinated to a cyclooctadiene ligand. The cyclooctadiene ligands are known for their ability to stabilize metal centers and facilitate various catalytic processes. This compound is often studied in the context of organometallic chemistry and catalysis, particularly in reactions involving olefins and other unsaturated substrates. Its properties include potential applications in asymmetric synthesis and catalysis due to the chiral environment created by the cyclooctadiene ligands. Additionally, the presence of the methoxy groups can influence the electronic properties and reactivity of the rhodium centers, making it a subject of interest for researchers exploring metal-ligand interactions and catalytic mechanisms. Overall, this compound exemplifies the intricate relationship between metal coordination and organic ligand design in the field of organometallic chemistry.
Formula:C18H30O2Rh2
InChI:InChI=1S/2C8H12.2CH3O.2Rh/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H,3-6H2;2*1H3;;/q;;2*-1;2*+1
InChI key:InChIKey=BDQMDBOKWREKIT-UHFFFAOYSA-N
SMILES:C[O-]1[Rh+]234([O-](C)[Rh+]1567[CH]8=[CH]5CC[CH]6=[CH]7CC8)[CH]9=[CH]2CC[CH]3=[CH]4CC9
Synonyms:
  • 1,5-Cyclooctadiene, rhodium complex
  • Bis((1,5-cyclooctadiene)(μ-methanolato)rhodium)
  • Bis(1,5-cyclooctadiene)-di-μ-methoxodirhodium
  • Bis(1,5-cyclooctadiene)bis(μ-methanolato)dirhodium
  • Bis(1,5-cyclooctadiene)di-μ-methoxydirhodium
  • Bis(1,5-cyclooctadiene)dimethoxydirhodium
  • Bis(cyclooctadiene)bis(methoxy)dirhodium
  • Bis(η<sup>4</sup>-1,5-cyclooctadiene)-di-μ-methoxodirhodium
  • Bis(η<sup>4</sup>-1,5-cyclooctadiene)-di-μ-methoxydirhodium
  • Bis[(1,2,5,6-Η)-1,5-Cyclooctadiene]Di-Μ-Methoxydirhodium
  • See more synonyms
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