CAS 12150-46-8
:1,1'-bis(diphenyphosphino)ferrocene
Description:
1,1'-Bis(diphenylphosphino)ferrocene, with the CAS number 12150-46-8, is a bimetallic organophosphorus compound characterized by its unique structure, which features a ferrocene core substituted with two diphenylphosphino groups. This compound exhibits notable properties such as high thermal stability and solubility in organic solvents, making it useful in various chemical applications, particularly in catalysis and coordination chemistry. The presence of the ferrocene moiety imparts a degree of redox activity, allowing it to participate in electron transfer processes. Additionally, the diphenylphosphino groups enhance its ability to coordinate with transition metals, facilitating the formation of metal complexes. Its steric and electronic properties can be tuned by modifying the phosphine groups, which can influence its reactivity and selectivity in catalytic reactions. Overall, 1,1'-bis(diphenylphosphino)ferrocene is a valuable compound in synthetic chemistry, particularly in the development of new catalysts and materials.
Formula:C34H28FeP2
InChI:InChI=1/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;/rC34H28FeP2/c1-5-15-27(16-6-1)36(28-17-7-2-8-18-28)33-25-13-23-31(33)35-32-24-14-26-34(32)37(29-19-9-3-10-20-29)30-21-11-4-12-22-30/h1-26,31-32H
InChI key:InChIKey=KZPYGQFFRCFCPP-UHFFFAOYSA-N
SMILES:P([C-]12[Fe+2]3456789([C-]%10(P(C%11=CC=CC=C%11)C%12=CC=CC=C%12)[CH]3=[CH]4[CH]5=[CH]6%10)[CH]1=[CH]7[CH]8=[CH]92)(C%13=CC=CC=C%13)C%14=CC=CC=C%14
Synonyms:- 1,1'-Bis(diphenylphosphino)ferrocene
- 1,1'-Ferrocenebis(diphenylphosphine)
- 1,1'-Ferrocenediyl-bis(diphenylphosphine)
- 1,10-Bis(diphenylphosphanyl)ferrocene
- 1,1′-Ferrocendiylbis(diphenylphosphine)
- 1-Cyclopenta-2,4-Dienyl-Diphenyl-Phosphane Iron
- Bis(2-Diphenylphosphanylcyclopenta-2,4-Dien-1-Yl)Iron
- Dppf
- Ferrocene, 1,1′-bis(diphenylphosphino)-
- NSC 238923
- Phosphine, 1,1′-ferrocenediylbis[diphenyl-
- Phosphine, cyclopentadienyldiphenyl-, iron deriv.
- Zirconium ionophore I
- 1,1'-Bis(diphenylphosphino)ferrocene, C 73.4%, H 5.2%
- DPPF/1,1''-BIS(DIPHENYLPHOSPHINO) FERROCENE
- 1,1'-Bis(diphenylphosphino)ferrocene,99%DPPF
- 1,1'-bis(diphenyphosphino)ferrocene
- 1,1'-bis(diphenyphosphino)ferrocene(dppf)
- 1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE
- 1,1μ-Ferrocenebis(diphenylphosphine), 1,1μ-Ferrocenediyl-bis(diphenylphosphine)
- 1,1'-Bis(diphenylphosphino) ferrocene, Catalyst Grade
- 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF)
- 1,1''-BIS-(DIPHENYLPHOSPHINO)-FEROCENE
- See more synonyms
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Found 11 products.
1,1'-Bis(diphenylphosphino)ferrocene
CAS:Formula:C34H28FeP2Purity:>96.0%(T)Color and Shape:Light yellow to Brown powder to crystalineMolecular weight:554.391,1'-Bis(diphenylphosphino)ferrocene, 97%
CAS:1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synth
Formula:C34H28FeP2Purity:97%Color and Shape:Yellow to orange, Crystalline powder or powderMolecular weight:554.391,1'-Bis(diphenylphosphino)ferrocene, 99% DPPF
CAS:1,1'-Bis(diphenylphosphino)ferrocene, 99% DPPF
Formula:(C6H5)2PC5H4FeC5H4P(C6H5)2Purity:99%Color and Shape:yellow to orange xtl.Molecular weight:554.39Ferrocene, 1,1'-bis(diphenylphosphino)-
CAS:Formula:C34H28FeP2Purity:97%Color and Shape:SolidMolecular weight:554.37861,1'-Bis(diphenylphosphino)ferrocene
CAS:1,1'-Bis(diphenylphosphino)ferroceneFormula:C34H28FeP2Purity:98%Color and Shape: yellow solidMolecular weight:554.37864g/mol1,1''-Bis(diphenylphosphino)ferrocene
CAS:Formula:C34H28FeP2Purity:≥ 98.0%Color and Shape:Yellow to dark yellow or orange powderMolecular weight:554.401,1′-Bis(diphenylphosphino)ferrocene
CAS:Formula:C34H28FeP2Purity:98.0%Color and Shape:SolidMolecular weight:554.3911,1-Bis(diphenylphosphino)ferrocene
CAS:Used for palladium-catalyzed cross-coupling reactionsFormula:C34H28FeP2Purity:Min. 95%Color and Shape:PowderMolecular weight:554.38 g/mol1,1’-Bis(diphenylphosphino)ferrocene
CAS:Controlled ProductApplications Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which is a popular reagent for palladium-catalyzed coupling reactions.
References Nataro, C., et al.: J. Chem. Ed., 86, 1412 (2009),Formula:C34H28FeP2Color and Shape:NeatMolecular weight:554.38DPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98%
CAS:Formula:C34H28FeP2Purity:min. 98%Color and Shape:Orange yellow, PowderMolecular weight:554.38
