CAS 12150-46-8

1,1'-bis(diphenyphosphino)ferrocene

Description:

1,1'-Bis(diphenylphosphino)ferrocene, with the CAS number 12150-46-8, is a bimetallic organophosphorus compound characterized by its unique structure, which features a ferrocene core substituted with two diphenylphosphino groups. This compound exhibits notable properties such as high thermal stability and solubility in organic solvents, making it useful in various chemical applications, particularly in catalysis and coordination chemistry. The presence of the ferrocene moiety imparts a degree of redox activity, allowing it to participate in electron transfer processes. Additionally, the diphenylphosphino groups enhance its ability to coordinate with transition metals, facilitating the formation of metal complexes. Its steric and electronic properties can be tuned by modifying the phosphine groups, which can influence its reactivity and selectivity in catalytic reactions. Overall, 1,1'-bis(diphenylphosphino)ferrocene is a valuable compound in synthetic chemistry, particularly in the development of new catalysts and materials.

Formula: C₃₄H₂₈FeP₂

InChI: InChI=1/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;/rC34H28FeP2/c1-5-15-27(16-6-1)36(28-17-7-2-8-18-28)33-25-13-23-31(33)35-32-24-14-26-34(32)37(29-19-9-3-10-20-29)30-21-11-4-12-22-30/h1-26,31-32H

InChI key: InChIKey=KZPYGQFFRCFCPP-UHFFFAOYSA-N

SMILES: P([C-]12[Fe+2]3456789([C-]%10(P(C%11=CC=CC=C%11)C%12=CC=CC=C%12)[CH]3=[CH]4[CH]5=[CH]6%10)[CH]1=[CH]7[CH]8=[CH]92)(C%13=CC=CC=C%13)C%14=CC=CC=C%14

Synonyms:

• 1,1'-Bis(diphenylphosphino)ferrocene
• 1,1'-Ferrocenebis(diphenylphosphine)
• 1,1'-Ferrocenediyl-bis(diphenylphosphine)
• 1,10-Bis(diphenylphosphanyl)ferrocene
• 1,1′-Ferrocendiylbis(diphenylphosphine)
• 1-Cyclopenta-2,4-Dienyl-Diphenyl-Phosphane Iron
• Bis(2-Diphenylphosphanylcyclopenta-2,4-Dien-1-Yl)Iron
• Dppf
• Ferrocene, 1,1′-bis(diphenylphosphino)-
• NSC 238923
• Phosphine, 1,1′-ferrocenediylbis[diphenyl-
• Phosphine, cyclopentadienyldiphenyl-, iron deriv.
• Zirconium ionophore I
• 1,1'-Bis(diphenylphosphino)ferrocene, C 73.4%, H 5.2%
• DPPF/1,1''-BIS(DIPHENYLPHOSPHINO) FERROCENE
• 1,1'-Bis(diphenylphosphino)ferrocene,99%DPPF
• 1,1'-bis(diphenyphosphino)ferrocene
• 1,1'-bis(diphenyphosphino)ferrocene(dppf)
• 1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE
• 1,1μ-Ferrocenebis(diphenylphosphine), 1,1μ-Ferrocenediyl-bis(diphenylphosphine)
• 1,1'-Bis(diphenylphosphino) ferrocene, Catalyst Grade
• 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF)
• 1,1''-BIS-(DIPHENYLPHOSPHINO)-FEROCENE

1,1'-Bis(diphenylphosphino)ferrocene

CAS: 12150-46-8

Formula: C₃₄H₂₈FeP₂

Purity: >96.0%(T)

Color and Shape: Light yellow to Brown powder to crystaline

Molecular weight: 554.39

Ref: 3B-B2027

1,1'-Bis(diphenylphosphino)ferrocene, 97%

CAS: 12150-46-8

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synth

Formula: C₃₄H₂₈FeP₂

Purity: 97%

Color and Shape: Yellow to orange, Crystalline powder or powder

Molecular weight: 554.39

Ref: 02-B21166

1,1'-Bis(diphenylphosphino)ferrocene, 99% DPPF

CAS: 12150-46-8

1,1'-Bis(diphenylphosphino)ferrocene, 99% DPPF

Formula: (C₆H₅)₂PC₅H₄FeC₅H₄P(C₆H₅)₂

Purity: 99%

Color and Shape: yellow to orange xtl.

Molecular weight: 554.39

Ref: 08-26-0270

Ferrocene, 1,1'-bis(diphenylphosphino)-

CAS: 12150-46-8

Formula: C₃₄H₂₈FeP₂

Purity: 97%

Color and Shape: Solid

Molecular weight: 554.3786

Ref: IN-DA00153T

1,1'-Bis(diphenylphosphino)ferrocene

CAS: 12150-46-8

1,1'-Bis(diphenylphosphino)ferrocene

Formula: C₃₄H₂₈FeP₂

Purity: 98%

Color and Shape: yellow solid

Molecular weight: 554.37864g/mol

Ref: 54-OR1945

1,1''-Bis(diphenylphosphino)ferrocene

CAS: 12150-46-8

Formula: C₃₄H₂₈FeP₂

Purity: ≥ 98.0%

Color and Shape: Yellow to dark yellow or orange powder

Molecular weight: 554.40

Ref: 7W-GK1370

1,1′-Bis(diphenylphosphino)ferrocene

CAS: 12150-46-8

Formula: C₃₄H₂₈FeP₂

Purity: 98.0%

Color and Shape: Solid

Molecular weight: 554.391

Ref: 10-F044344

1,1-Bis(diphenylphosphino)ferrocene

CAS: 12150-46-8

Used for palladium-catalyzed cross-coupling reactions

Formula: C₃₄H₂₈FeP₂

Purity: Min. 95%

Color and Shape: Powder

Molecular weight: 554.38 g/mol

Ref: 3D-FB11131

1,1’-Bis(diphenylphosphino)ferrocene

Controlled Product

CAS: 12150-46-8

Applications Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which is a popular reagent for palladium-catalyzed coupling reactions.
References Nataro, C., et al.: J. Chem. Ed., 86, 1412 (2009),

Formula: C₃₄H₂₈FeP₂

Color and Shape: Neat

Molecular weight: 554.38

Ref: TR-B430350

DPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98%

CAS: 12150-46-8

Formula: C₃₄H₂₈FeP₂

Purity: min. 98%

Color and Shape: Orange yellow, Powder

Molecular weight: 554.38

Ref: SR-23660