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CAS 12154-95-9

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Iron, di-μ-carbonyldicarbonylbis(η5-2,4-cyclopentadien-1-yl)di-, (Fe-Fe)

Description:
Iron, di-μ-carbonyldicarbonylbis(η5-2,4-cyclopentadien-1-yl)di-, commonly referred to as a complex of iron, features a unique coordination environment characterized by its bridging carbonyl groups and cyclopentadienyl ligands. This compound is notable for its use in organometallic chemistry, where it exhibits interesting electronic and structural properties due to the presence of both carbonyl and cyclopentadienyl ligands. The iron centers in this complex are typically in a low oxidation state, which contributes to its reactivity and potential applications in catalysis. The presence of the cyclopentadienyl groups enhances the stability of the complex and allows for π-backbonding interactions with the carbonyl ligands, influencing the overall electronic structure. Additionally, this compound may exhibit interesting magnetic properties due to the presence of iron, which is known for its ferromagnetic characteristics. Overall, this iron complex serves as a valuable model for studying metal-ligand interactions and the behavior of transition metal complexes in various chemical environments.
Formula:C14H10Fe2O4
InChI:InChI=1S/2C5H5.4CO.2Fe/c2*1-2-4-5-3-1;4*1-2;;/h2*1-5H;;;;;;/q2*-1;;;2*-2;2*+3
InChI key:InChIKey=CIDIJZKXTFILKY-UHFFFAOYSA-N
SMILES:C(#O)[Fe+3]123456([Fe+3]789%10(C#O)([C-2]1=O)([C-2]2=O)[CH-]%11[CH]7=[CH]8[CH]9=[CH]%10%11)[CH-]%12[CH]3=[CH]4[CH]5=[CH]6%12
Synonyms:
  • Bis(cyclopentadienyldicarbonyliron)
  • Bis(cyclopentadienyliron dicarbonyl)
  • Bis(dicarbonyl(η5-cyclopentadienyl)iron)
  • Bis(dicarbonyl(η<sup>5</sup>-cyclopentadienyl)iron)
  • Bis(dicarbonyl-π-cyclopentadienyliron)
  • Bis(π-cyclopentadienyldicarbonyliron)
  • Bis(π-cyclopentadienylirondicarbonyl)
  • Bis[dicarbonyl(π-cyclopentadienyl)iron(II)]
  • Cyclopentadienyldicarbonyliron dimer
  • Cyclopentadienylirondicarbonyl dimer
  • See more synonyms
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