CAS 122092-51-7

[μ-[1,1′-Bis(diphenylphosphino-κP)ferrocene]]dichlorodigold

Description:

The chemical substance known as "[μ-[1,1′-Bis(diphenylphosphino-κP)ferrocene]]dichlorodigold" is a coordination compound featuring a unique structure that incorporates ferrocene, a metallocene with iron, and diphenylphosphine ligands. This compound is characterized by its bimetallic nature, where two gold atoms are bridged by a ferrocene unit, with each gold atom coordinated to a chloride ion. The presence of diphenylphosphine ligands enhances the stability and reactivity of the gold centers, making it a subject of interest in organometallic chemistry and catalysis. The compound exhibits interesting electronic properties due to the ferrocene moiety, which can facilitate electron transfer processes. Additionally, its potential applications in catalysis, materials science, and as a precursor for gold nanoparticles highlight its significance in both academic and industrial research. The compound's unique structural features and the interplay between its metal centers and ligands contribute to its reactivity and functional properties, making it a valuable subject of study in the field of coordination chemistry.

Formula: C₃₄H₂₈Au₂Cl₂FeP₂

InChI: InChI=1S/2C17H14P.2Au.2ClH.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;;/h2*1-14H;;;2*1H;/q2*-1;2*+1;;;+2/p-2

InChI key: InChIKey=ZIKZUJZWYWYNGL-UHFFFAOYSA-L

SMILES: [P]([Au+][Cl-])([C-]12[Fe+2]3456789([C-]%10([P]([Au+][Cl-])(C%11=CC=CC=C%11)C%12=CC=CC=C%12)[CH]3=[CH]4[CH]5=[CH]6%10)[CH]1=[CH]7[CH]8=[CH]92)(C%13=CC=CC=C%13)C%14=CC=CC=C%14

Synonyms:

• [μ-[1,1′-Bis(diphenylphosphino-κP)ferrocene]]dichlorodigold
• Gold, [μ-[1,1′-bis(diphenylphosphino)ferrocene-P:P′]]dichlorodi-
• Gold, [μ-[1,1′-bis(diphenylphosphino-κP)ferrocene]]dichlorodi-
• (1,1′-Bis(diphenylphosphino)ferrocene)dichlorodigold
• Ferrocene, 1,1′-bis(diphenylphosphino)-, gold complex

Bis(chlorogold(I)) [1,1'-bis(diphenylphosphino)ferrocene]

CAS: 122092-51-7

Formula: C₃₄H₂₂Au₂Cl₂FeP₂

Molecular weight: 1013.1701

Ref: IN-DA0016QM