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CAS 12245-39-5

:

[(1,2,5,6-η)-1,5-Cyclooctadiene](2,4-pentanedionato-κO2,κO4)rhodium

Description:
The chemical substance known as [(1,2,5,6-η)-1,5-Cyclooctadiene](2,4-pentanedionato-κO2,κO4)rhodium, with the CAS number 12245-39-5, is a coordination complex of rhodium. It features a cyclooctadiene ligand that is coordinated in a η^6 fashion, which contributes to its stability and reactivity. The complex also includes a bidentate ligand, 2,4-pentanedione, which coordinates to the rhodium center through two oxygen atoms, enhancing the overall stability of the compound. This rhodium complex is often studied for its catalytic properties, particularly in organic synthesis and hydroformylation reactions. Its unique structure allows for specific interactions with substrates, making it valuable in various chemical transformations. The compound is typically characterized by its distinct spectral properties, including NMR and IR spectroscopy, which provide insights into its molecular structure and bonding. Additionally, it may exhibit interesting reactivity patterns due to the presence of both the cyclooctadiene and the diketone ligands, making it a subject of interest in coordination chemistry and catalysis research.
Formula:C13H19O2Rh
InChI:InChI=1S/C8H12.C5H7O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3H,1-2H3;/q;-1;+1
InChI key:InChIKey=ULVMWGPNSJNVMV-UHFFFAOYSA-N
SMILES:CC1=O[Rh+]234([CH]5=[CH]2CC[CH]3=[CH]4CC5)O=C(C)[CH-]1
Synonyms:
  • (1,5-Cyclooctadiene)(2,4-pentadionato)rhodium(I)
  • (1,5-Cyclooctadiene)(acetylacetonate)rhodium
  • (1,5-Cyclooctadiene)(acetylacetonato)rhodium(I)
  • (1,5-Cyclooctadiene)rhodium acetylacetonate
  • (1-Methyl-3-Oxoniumylidene-Butylidene)Oxonium
  • (1Z,5Z)-cycloocta-1,5-diene
  • (Acetylacetonato)(1,5-cyclooctadiene)rhodium
  • (Acetylacetonato)(cyclooctadiene)rhodium
  • (Acetylacetonato)(η<sup>4</sup>-1,5-cyclooctadiene)rhodium
  • 1,5-Cyclooctadiene, rhodium complex
  • See more synonyms
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