CymitQuimica logo

CAS 12257-42-0

:

bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorodirhodium

Description:
Bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorodirhodium, with the CAS number 12257-42-0, is a coordination compound featuring a rhodium metal center coordinated by two bidentate ligands derived from bicyclo[2.2.1]hepta-2,5-diene. This compound exhibits unique structural characteristics due to the presence of the bicyclic diene ligands, which contribute to its stability and reactivity. The rhodium atoms are bridged by two chloride ions, forming a dinuclear complex that can participate in various catalytic processes, particularly in organic synthesis and polymerization reactions. The compound is typically characterized by its distinctive spectral properties, including UV-Vis and NMR spectroscopy, which provide insights into its electronic structure and bonding environment. Additionally, its reactivity can be influenced by the presence of substituents on the diene ligands, making it a subject of interest in coordination chemistry and catalysis research. Overall, this compound exemplifies the intricate interplay between metal centers and organic ligands in transition metal chemistry.
Formula:C14H16Cl2Rh2
InChI:InChI=1S/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2
InChI key:InChIKey=RXDWVIOULPVOEO-UHFFFAOYSA-L
SMILES:[Rh+]1234([CH]5=[CH]1C6[CH]2=[CH]3C5C6)[Cl-][Rh+]789([Cl-]4)[CH]%10=[CH]7C%11[CH]8=[CH]9C%10C%11
Synonyms:
  • (Bicyclo[2.2.1]Hepta-2,5-Diene)Chlororhodium(I) Dimer
  • (Bicyclo[2.2.1]hepta-2,5-diene)rhodium (I) chloride dimer
  • (η<sup>4</sup>-Norbornadiene)rhodium chloride dimer
  • Bicyclo[2.2.1]hepta-2,5-diene, rhodium complex
  • Bis((2,3,5,6-eta)-bicyclo(2.2.1)hepta-2,5-diene)di-mu-chlorodirhodium
  • Bis((μ-chloro)(2,5-norbornadiene)rhodium)
  • Bis((μ-chloro)(norbornadiene)rhodium)
  • Bis(chloro(η<sup>4</sup>-norbornadiene)rhodium)
  • Bis(μ-chloro)bis(norbornadiene)dirhodium
  • Bis(μ-chloro)bis[(norbornadiene)rhodium]
  • See more synonyms
Sort by
Purity (%)
0
100
|
0
|
50
|
90
|
95
|
100
Found 6 products.