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CAS 12279-09-3

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Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium

Description:
Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium, with the CAS number 12279-09-3, is a coordination compound featuring rhodium as the central metal. This complex is characterized by its unique structure, which includes two rhodium atoms bridged by two chloride ions (μ-chloride), and coordinated to four cyclooctene ligands in a bidentate fashion. The cyclooctene ligands contribute to the compound's stability and reactivity, allowing it to participate in various chemical reactions, particularly in catalysis. The presence of the rhodium metal imparts significant catalytic properties, making this compound of interest in organic synthesis and industrial applications. Additionally, the compound's geometry is influenced by the steric and electronic effects of the cyclooctene ligands, which can affect its reactivity and interaction with other substrates. Overall, Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium exemplifies the intricate interplay between metal coordination and ligand design in transition metal chemistry.
Formula:C32H56Cl2Rh2
InChI:InChI=1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2
InChI key:InChIKey=GQPAPAIPOLEZHT-UHFFFAOYSA-L
SMILES:[Rh+]123([Cl-][Rh+]45([Cl-]1)([CH]6=[CH]4CCCCCC6)[CH]7=[CH]5CCCCCC7)([CH]8=[CH]2CCCCCC8)[CH]9=[CH]3CCCCCC9
Synonyms:
  • Bis((μ-chloro)bis(cyclooctene)rhodium)
  • Bis((μ-chloro)bis(η<sup>2</sup>-cyclooctene)rhodium)
  • Bis(chlorobis(cyclooctene)rhodium)
  • Bis(μ-chloro)tetracyclooctenedirhodium
  • Chlorobis(cyclooctene)rhodium dimer
  • Chlorobis(cyclooctene)rhodium(I)
  • Cyclooctene, rhodium complex
  • Di-μ-Chlorotetrakis(cyclooctene)dirhodium
  • Di-μ-chlorotetrakis(η<sup>2</sup>-cyclooctene)dirhodium(I)
  • Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]dirhodium
  • See more synonyms
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