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CAS 12289-94-0

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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)

Description:
Ruthenium II cyclooctadiene bis-(2,2,6,6-tetramethylheptanedionate), commonly referred to as Ru(COD)(tmhd)2, is a coordination compound featuring ruthenium in a +2 oxidation state. This complex is characterized by its coordination with cyclooctadiene (COD) and two bidentate ligands, 2,2,6,6-tetramethylheptanedionate (tmhd). The structure typically exhibits a square planar geometry around the ruthenium center, which is common for d6 metal complexes. The presence of the bulky tmhd ligands contributes to the compound's stability and solubility in organic solvents. Ru(COD)(tmhd)2 is notable for its applications in catalysis, particularly in organic synthesis and polymerization reactions, due to its ability to facilitate various transformations. Additionally, it may exhibit interesting electronic and optical properties, making it a subject of research in materials science. The compound is generally handled with care, as with many metal complexes, due to potential toxicity and reactivity.
Formula:C8H14Ru·C8H12
InChI:InChI=1/C8H12.2C4H7.Ru/c1-2-4-6-8-7-5-3-1;2*1-4(2)3;/h1-2,7-8H,3-6H2;2*1-2H2,3H3;/b2-1-,8-7-;;;/rC8H14Ru.C8H12/c1-7(2)5-9-6-8(3)4;1-2-4-6-8-7-5-3-1/h1,3,5-6H2,2,4H3;1-2,7-8H,3-6H2/b;2-1-,8-7-
SMILES:C=C(C)C[Ru]CC(=C)C.C1=CCCC=CCC1
Synonyms:
  • Bis(2-Methylallyl)(1,5-Cyclooctadiene)Ruthenium(Ii)
  • Bis-(2-Methylallyl)Cycloocta-1,5-Diene Ruthenium (Ii) Complex
  • Bis(2-Methylallyl) (1,5-Cyclooctadiene)&
  • Bis(2-Methylallyl)(1,5-Cyclooctadiene)R&
  • RutheniumCyclooctadieneBis(2,2,6,6-Tetramethylheptanedionate)
  • Bis(2-Methylallyl)(1,5-Cyclooctadiene)Ruthenium(Ii),Min.
  • Bis-(2-methylallyl)cycloocta-1,5-diene ruthenium(II) complex, 30-32% Ru
  • Ruthenium cyclooctadiene bis(2,2,6,6-tetramethylheptanedionate)
  • Bis(2-Methylprop-2-Enyl)Ruthenium
  • (1Z,5Z)-cycloocta-1,5-diene
  • See more synonyms
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