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CAS 123333-45-9

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[P,P'-1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE][P-1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE]PALLADIUM (0)

Description:
[P,P'-1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE][P-1,3-BIS(DI-I-PROPYLPHOSPHINO)PROPANE]PALLADIUM (0), commonly referred to as Pd(dppp) or a similar nomenclature, is a palladium complex featuring a bidentate ligand derived from 1,3-bis(di-i-propylphosphino)propane. This compound is characterized by its coordination of palladium in the zero oxidation state, which is crucial for its catalytic properties, particularly in cross-coupling reactions such as Suzuki and Heck reactions. The bulky di-i-propylphosphino groups enhance the stability of the palladium center and provide steric hindrance, which can influence the selectivity and reactivity of the catalyst. This complex is typically soluble in organic solvents, making it suitable for various organic synthesis applications. Its properties, including thermal stability and reactivity, can be influenced by the electronic and steric effects of the phosphine ligands. Overall, this palladium complex is significant in the field of organometallic chemistry and catalysis, facilitating a range of chemical transformations in synthetic organic chemistry.
Formula:C30H68P4Pd
InChI:InChI=1/2C15H34P2.Pd/c2*1-12(2)16(13(3)4)10-9-11-17(14(5)6)15(7)8;/h2*12-15H,9-11H2,1-8H3;
SMILES:CC(C)P(CCCP(C(C)C)C(C)C)C(C)C.CC(C)P(CCCP(C(C)C)C(C)C)C(C)C.[Pd]
Synonyms:
  • [P,P'-1,3-bis(di-i-propylphosphino)propane][P-1,3-bis(di-i-propylphosphino)propane]palladium(0),98%
  • Palladium - Propane-1,3-Diylbis[Bis(1-Methylethyl)Phosphane] (1:2)
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