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CAS 12354-84-6
:Iridium, di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
Description:
Iridium, di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di- is a complex organometallic compound featuring iridium as the central metal atom. This compound is characterized by its coordination with multiple ligands, specifically chlorides and cyclopentadienyl derivatives, which contribute to its unique structural and electronic properties. The presence of the pentamethyl substituents on the cyclopentadienyl rings enhances the stability and solubility of the complex. Iridium complexes are known for their catalytic properties, particularly in organic synthesis and in the field of materials science. The di-μ-chloro bridging indicates that the chlorides are acting as bridging ligands between iridium centers, which can influence the reactivity and coordination environment of the metal. Overall, this compound exemplifies the intricate interplay of metal-ligand interactions that define the behavior of transition metal complexes in various chemical applications.
Formula:C20H30Cl4Ir2
InChI:InChI=1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q2*-1;;;;;2*+3/p-4
InChI key:InChIKey=MMAGMBCAIFVRGJ-UHFFFAOYSA-J
SMILES:[Cl-][Ir+3]12345(C=6(C)C1(C)=C2(C)[C-]3(C)C46C)[Cl-][Ir+3]789%10([Cl-])([Cl-]5)[C-]%11(C)C7(C)=C8(C)C9(C)=C%10%11C
Synonyms:- (Ir(Cp*)Cl<sub>2</sub>)<sub>2</sub>
- (Pentamethylcyclopentadienyl)iridium dichloride dimer
- (Pentamethylcyclopentadienyl)iridium(III)Dichloride Dimer
- (η<sup>5</sup>-Pentamethylcyclopentadienyl)iridium dichloride dimer
- 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, iridium complex
- Bis((μ-chloro)chloro(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium)
- Bis(chloro(μ<sub>2</sub>-chloro)(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium)
- Bis(dichloro(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium)
- Bis(dichloro(η<sup>5</sup>-η-pentamethylcyclopentadienyl)iridium)
- Bis(pentamethylcyclopentadiene)tetrachlorodiiridium
- Bis(pentamethylcyclopentadienyliridium dichloride)
- Bis(μ-chloro)bis[chloro(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium]
- Bis[dichloro(pentamethylcyclopentadienyl)iridium]
- Di-μ-chlorobis(chloro(η<sup>5</sup>-pentamethylcyclopentadienyl)iridium)
- Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)diiridium
- Dichloro(pentamethylcyclopentadienyl)iridium dimer
- Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
- Dichlorobis(μ<sub>2</sub>-chloro)bis(η<sup>5</sup>-pentamethylcyclopentadienyl)diiridium
- Dichlorodi-μ-chlorobis(η<sup>5</sup>-pentamethylcyclopentadienyl)diiridium
- Dichloropentamethylcyclopentadienyliridiumdimer
- Iridium, di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
- Pentamethylcyclopentadienyl)iridium(III) chloride dimer
- Pentamethylcyclopentadienyliridium(III) chloride,dimer
- Pentamethylcyclopentadienyliridium(III) dichloride dimer
- Tetrachlorobis(pentamethylcyclopentadienyl)diiridium
- Tetrachlorobis(η<sup>5</sup>-pentamethylcyclopentadienyl)diiridium
- See more synonyms
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Found 9 products.
(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer
CAS:Formula:C20H30Cl4Ir2Purity:>95.0%(T)Color and Shape:Light yellow to Brown powder to crystalMolecular weight:796.69Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
CAS:Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some
Formula:C20H30Cl4Ir2Color and Shape:Orange, Crystals or crystalline powderMolecular weight:796.69Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%
CAS:Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer, 98%
Formula:(CH3)5C5IrCl2Purity:98%Color and Shape:orange xtl.Molecular weight:796.67Iridium,di-m-chlorodichlorobis[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
CAS:Formula:C20H30Cl4Ir2Purity:98%Color and Shape:SolidMolecular weight:796.6982(Pentamethylcyclopentadienyl)iridium(III) dichloride dimer
CAS:(Pentamethylcyclopentadienyl)iridium(III) dichloride dimerFormula:C20H30Cl4Ir2Purity:98%,Ir:48%,high pureColor and Shape: orange powderMolecular weight:796.70g/molPentamethylcyclopentadienyliridium(III) chloride, dimer
CAS:Formula:C20H30Cl4Ir2Purity:≥ 97.0%Color and Shape:Yellow to orange powderMolecular weight:796.70Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
CAS:Controlled ProductApplications Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is commonly found to be used as a catalyst in reactions, and the synthesis oxidative arylation with indoles, azobenzene derivatives., and ortho-alkynylated arylalkylamines.
References Li, G., et al.: Org. Lett., 20, 2454-58 (2018); Tindall, D.J., et al.: J. Am. Chem. Soc., 140, 1884-93 (2018); Chen, X., et al.: Org. Lett., 20, 1171-74 (2018);Formula:C20H30Cl4Ir2Color and Shape:NeatMolecular weight:796.7DICHLORO(PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III) DIMER
CAS:Formula:C20H30Cl4Ir2Purity:98%Molecular weight:796.69Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer
CAS:Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer (DCPI) is a synthetic ligand that can be used in biomolecular and chemical applications. DCPI has been shown to be stable in the presence of chloride, which is needed for many catalytic reactions. This compound has high activity as a transfer agent and is also able to transfer amines and cyclic compounds. DCPI can be used in fluorescence-based assays, due to its strong fluorescence emission.Formula:C20H30Cl4Ir2Purity:Min. 95%Color and Shape:PowderMolecular weight:796.7 g/mol
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