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CAS 12354-85-7

:

Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium]

Description:
Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium], commonly referred to as bis(pentamethylcyclopentadienyl)rhodium(II) dichloride, is a coordination compound featuring rhodium as the central metal atom. This compound is characterized by its unique pentamethylcyclopentadienyl ligands, which provide a stable η5 coordination mode, enhancing the overall stability and reactivity of the complex. The dichloro ligands contribute to its coordination environment, making it a versatile precursor in various catalytic applications, particularly in organic synthesis and polymerization reactions. The compound is typically handled under inert atmospheres due to its sensitivity to moisture and air, which can lead to degradation. Its distinctive structure allows for interesting electronic properties, making it a subject of study in organometallic chemistry. Additionally, it exhibits notable catalytic activity, which is of interest in the development of new catalytic systems. Safety precautions should be observed when handling this compound, as it may pose health risks if ingested or inhaled.
Formula:C20H30Cl4Rh2
InChI:InChI=1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q2*-1;;;;;2*+3/p-4
InChI key:InChIKey=AUBQNRPCZLEJIZ-UHFFFAOYSA-J
SMILES:[Cl-][Rh+3]12345(C=6(C)C1(C)=C2(C)[C-]3(C)C46C)[Cl-][Rh+3]789%10([Cl-])([Cl-]5)[C-]%11(C)C7(C)=C8(C)C9(C)=C%10%11C
Synonyms:
  • (Pentamethylcyclopentadienyl)rhodium dichloride dimer
  • (Pentamethylcyclopentadienyl)rhodium(III)DichlorideDimer
  • (η<sup>5</sup>-Pentamethylcyclopentadienyl)rhodium dichloride dimer
  • 1,2,3,4,5-Pentamethylcyclopentane-1,2,3,4,5-Pentayl - Dichlororhodiumato(4-) (2:2)
  • 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex
  • Bis(chloro(μ-chloro)(η<sup>5</sup>-pentamethylcyclopentadienyl)rhodium)
  • Bis(dichloro(pentamethylcyclopentadienyl)rhodium)
  • Bis(pentamethylcyclopentadienylrhodium dichloride)
  • Bis(μ-chloro)bis(chloro(η<sup>5</sup>-pentamethylcyclopentadienyl)rhodium)
  • Bis[(Pentamethylcyclopentadienyl)Dichloro-Rhodium]
  • See more synonyms
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