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(R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthyl

CAS 126613-06-7: (R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthyl

Description:(R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthyl, with CAS number 126613-06-7, is a chiral compound notable for its application in asymmetric synthesis and catalysis. This substance features a binaphthyl backbone, which contributes to its rigidity and stereochemical properties, making it an effective chiral auxiliary. The presence of two trifluoromethanesulfonyloxy groups enhances its reactivity, particularly in electrophilic substitution reactions. The trifluoromethanesulfonyl (triflate) groups are known for their excellent leaving ability, facilitating various transformations in organic synthesis. Additionally, the compound exhibits significant solubility in polar organic solvents, which is advantageous for its use in diverse chemical reactions. Its chirality allows for the preferential formation of one enantiomer over another in reactions, making it valuable in the synthesis of pharmaceuticals and fine chemicals. Overall, this compound is characterized by its unique structural features, high reactivity, and utility in asymmetric synthesis, contributing to its importance in modern organic chemistry.

Formula:C22H12F6O6S2

InChI:InChI=1S/C22H12F6O6S2/c23-21(24,25)35(29,30)33-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)34-36(31,32)22(26,27)28/h1-12H

InChI key:InChIKey=OYJLCOSEYYZULE-UHFFFAOYSA-N

SMILES:O=S(=O)(OC=1C=CC=2C=CC=CC2C1C3=C(OS(=O)(=O)C(F)(F)F)C=CC=4C=CC=CC43)C(F)(F)F

  • Synonyms:
  • (R)-(-)-1,1'-Bi-2-Naphthol Bis(Trifluoromethanesulfonate)
  • (R)-(-)-1,1'-Bi-2-Naphthyl Bis-Trifluoromethanesulfonate
  • (R)-(-)-1,1'-Binaphthyl-2,2'-Diyl Bis(Trifluoromethanesulfonate)
  • (R)-(-)-1,1'-Bis(2-Naphthol) Ditriflate
  • (R)-1,1'-Binaphthalene-2,2'-Diyl Bis(Trifluoromethanesulfonate)
  • (R)-1,1'-Binaphthyl-2,2'-Diyl Bis(Trifluoromethane)Sulphonate
  • (R)-1,1′-Binaphthalene-2,2′-diyl ditriflate
  • (R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthalene
  • (R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthyl
  • (R)-BINOL bis(triflate)
  • See more synonyms
  • (R)-BINOL ditriflate
  • 1,1'-Binaphthalene-2,2'-Diyl Bis(Trifluoromethanesulfonate)
  • Methanesulfonic acid, 1,1,1-trifluoro-, 1,1′-(1R)-[1,1′-binaphthalene]-2,2′-diyl ester, stereoisomer
  • Methanesulfonic acid, trifluoro-, (1R)-[1,1′-binaphthalene]-2,2′-diyl ester
  • Methanesulfonic acid, trifluoro-, [1,1′-binaphthalene]-2,2′-diyl ester, (R)-
  • Trifluoromethanesulfonic Acid 2'-Trifluoromethanesulfonyloxy-[1,1']Binaphthalenyl-2-Yl Ester
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(R)-(-)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate)

CAS:126613-06-7

Ref: 3B-B2230

1g63.00 €
Estimated delivery in United States, on Tuesday 22 Apr 2025
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(R)-(-)-1,1'-Bi-2-naphthol bis(trifluoromethanesulfonate), 98%

CAS:126613-06-7

Ref: 08-08-0160

1g116.00 €
5g432.00 €
250mg42.00 €
Estimated delivery in United States, on Thursday 24 Apr 2025
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Methanesulfonic acid, 1,1,1-trifluoro-, 1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diyl ester, stereoisomer

CAS:126613-06-7

Ref: IN-DA000T09

1g25.00 €
5g52.00 €
25g131.00 €
100g276.00 €
250mg25.00 €
Estimated delivery in United States, on Tuesday 29 Apr 2025
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(R)-1,1'-Binaphthyl-2,2'-diyl bis(trifluoromethanesulphonate)

CAS:126613-06-7

Ref: 54-PC0614

1g36.00 €
5g44.00 €
25g136.00 €
100g471.00 €
500g2,073.00 €
250mg37.00 €
Estimated delivery in United States, on Wednesday 30 Apr 2025
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(R)-(-)-1,1''-Bi-2-naphthyl bis-trifluoromethanesulfonate

CAS:126613-06-7

Ref: 7W-GK2218

Undefined sizeTo inquire
Estimated delivery in United States, on Wednesday 30 Apr 2025
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Ref: 10-F986604

1g25.00 €
5g50.00 €
10g88.00 €
25g172.00 €
100gTo inquire
Estimated delivery in United States, on Friday 9 May 2025
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(R)-(-)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate)

CAS:126613-06-7

Ref: 3D-FB59943

1gDiscontinuedRequest information
2gDiscontinuedRequest information
5gDiscontinuedRequest information
10gDiscontinuedRequest information
500mgDiscontinuedRequest information
Discontinued product
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