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CAS 126613-06-7

:

(R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthyl

Description:
(R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthyl, with CAS number 126613-06-7, is a chiral compound notable for its application in asymmetric synthesis and catalysis. This substance features a binaphthyl backbone, which contributes to its rigidity and stereochemical properties, making it an effective chiral auxiliary. The presence of two trifluoromethanesulfonyloxy groups enhances its reactivity, particularly in electrophilic substitution reactions. The trifluoromethanesulfonyl (triflate) groups are known for their excellent leaving ability, facilitating various transformations in organic synthesis. Additionally, the compound exhibits significant solubility in polar organic solvents, which is advantageous for its use in diverse chemical reactions. Its chirality allows for the preferential formation of one enantiomer over another in reactions, making it valuable in the synthesis of pharmaceuticals and fine chemicals. Overall, this compound is characterized by its unique structural features, high reactivity, and utility in asymmetric synthesis, contributing to its importance in modern organic chemistry.
Formula:C22H12F6O6S2
InChI:InChI=1S/C22H12F6O6S2/c23-21(24,25)35(29,30)33-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)34-36(31,32)22(26,27)28/h1-12H
InChI key:InChIKey=OYJLCOSEYYZULE-UHFFFAOYSA-N
SMILES:O(S(C(F)(F)F)(=O)=O)C1=C(C2=C(C=C1)C=CC=C2)C=3C4=C(C=CC3OS(C(F)(F)F)(=O)=O)C=CC=C4
Synonyms:
  • (R)-(-)-1,1'-Bi-2-Naphthol Bis(Trifluoromethanesulfonate)
  • (R)-(-)-1,1'-Bi-2-Naphthyl Bis-Trifluoromethanesulfonate
  • (R)-(-)-1,1'-Binaphthyl-2,2'-Diyl Bis(Trifluoromethanesulfonate)
  • (R)-(-)-1,1'-Bis(2-Naphthol) Ditriflate
  • (R)-1,1'-Binaphthalene-2,2'-Diyl Bis(Trifluoromethanesulfonate)
  • (R)-1,1'-Binaphthyl-2,2'-Diyl Bis(Trifluoromethane)Sulphonate
  • (R)-1,1′-Binaphthalene-2,2′-diyl ditriflate
  • (R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthalene
  • (R)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthyl
  • (R)-BINOL bis(triflate)
  • See more synonyms
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