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CAS 127593-28-6

:

[(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium (II) Chloride

Description:
[(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride, commonly referred to as Pd(dppf)Cl2, is a coordination complex featuring palladium as the central metal ion. This compound is characterized by its chiral bisphosphine ligand, which imparts stereochemical properties that are valuable in asymmetric catalysis. The palladium center typically exhibits a square planar geometry, which is common for palladium(II) complexes. The presence of diphenylphosphine groups enhances the electron-donating ability of the ligand, facilitating various catalytic reactions, particularly in cross-coupling processes such as Suzuki and Heck reactions. The compound is often utilized in organic synthesis due to its effectiveness in promoting C-C bond formation. Additionally, its solubility in organic solvents makes it suitable for a range of reaction conditions. Safety considerations should be taken into account, as palladium compounds can be toxic and should be handled with appropriate precautions. Overall, this complex is a significant reagent in modern synthetic chemistry, particularly in the development of chiral compounds.
Formula:C44H32Cl2P2Pd
Synonyms:
  • 2,2'-Bis(diphenylphosphino)1,1'-binaphthylpalladium(II) Chloride
  • palladium, [(1S)-[1,1'-Binaphthalene]-2,2'-Diylbis[diphenylphosphine-.KAPPA.P]]Dichloro-, (SP-4-2)-
  • Dichloro[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II)
  • [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride
  • Dichloro[(S)-(− )-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II)
  • [(S)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II)Chloride
  • [(S)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) Chloride
  • [(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) Chloride
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