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CAS 1277-47-0

:

Vanadocene

Description:
Vanadocene, with the CAS number 1277-47-0, is a metallocene compound that features vanadium in a sandwich structure, typically consisting of a vanadium atom sandwiched between two cyclopentadienyl anions. This compound is characterized by its distinctive coordination geometry, where the vanadium center exhibits a formal oxidation state of +4. Vanadocene is known for its vibrant color, which can range from orange to red, depending on its specific form and environment. It is generally stable under ambient conditions but can be sensitive to moisture and air, necessitating careful handling and storage in inert atmospheres. The compound has garnered interest in various fields, including catalysis and materials science, due to its unique electronic properties and potential applications in organic synthesis. Additionally, vanadocene's reactivity can be influenced by the presence of ligands, making it a subject of study for its potential use in organometallic chemistry and as a precursor for vanadium-based materials.
Formula:C10H10V
InChI:InChI=1S/2C5H5.V/c2*1-2-4-5-3-1;/h2*1-5H;/q2*-1;+2
InChI key:InChIKey=YXQWGVLNDXNSJJ-UHFFFAOYSA-N
SMILES:[V+2]12345678([CH]=9[CH]1=[CH]2[CH-]3[CH]49)[CH-]%10[CH]5=[CH]6[CH]7=[CH]8%10
Synonyms:
  • Bis(cyclopentadiene)vanadium
  • Bis(η<sup>5</sup>-cyclopentadienyl)vanadium
  • Bis(π-cyclopentadienyl)vanadium
  • Cyclopenta-1,3-Diene
  • Cyclopentane
  • Cyclopentane-1,2,3,4,5-Pentayl - Vanadium (2:1)
  • Di-π-Cyclopentadienylvanadium
  • Dicyclopentadienylvanadium
  • Vanadium
  • Vanadium, bis(η<sup>5</sup>-2,4-cyclopentadien-1-yl)-
  • See more synonyms
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