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(S)-(+)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)

CAS 128544-05-8: (S)-(+)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)

Description:(S)-(+)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) is a chiral compound commonly used in asymmetric synthesis and catalysis. It features a binaphthol backbone, which consists of two naphthol units connected by a single bond, and is functionalized with two trifluoromethanesulfonate (triflate) groups. The presence of these triflate groups enhances its reactivity and solubility in various organic solvents, making it a valuable reagent in organic chemistry. The compound exhibits strong optical activity due to its chiral nature, allowing it to selectively interact with other chiral molecules, which is crucial in the synthesis of enantiomerically pure compounds. Its triflate groups can act as excellent leaving groups in nucleophilic substitution reactions, facilitating the formation of carbon-carbon and carbon-heteroatom bonds. Additionally, (S)-(+)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) is often employed in the development of chiral catalysts and ligands, contributing to advancements in the field of asymmetric synthesis and pharmaceutical chemistry.

Formula:C22H12F6O6S2

InChI:InChI=1S/C22H12F6O6S2/c23-21(24,25)35(29,30)33-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)34-36(31,32)22(26,27)28/h1-12H

InChI key:InChIKey=OYJLCOSEYYZULE-UHFFFAOYSA-N

SMILES:O=S(=O)(OC=1C=CC=2C=CC=CC2C1C3=C(OS(=O)(=O)C(F)(F)F)C=CC=4C=CC=CC43)C(F)(F)F

  • Synonyms:
  • (S)-(+)-1,1'-Bi-2-naphthol bis(trifluoromethanesulfonate)
  • (S)-(+)-Binol-Tf2
  • (S)-1,1'-Binaphthalene-2,2'-diyl bis(trifluoromethanesulfonate)
  • (S)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthalene
  • (S)-2,2′-Bis(trifluoromethanesulfonyloxy)-1,1′-binaphthyl
  • (S)-BINOL bis(triflate)
  • 1,1'-Binaphthalen-2,2'-Diylbis(Trifluormethansulfonat)
  • Methanesulfonic acid, 1,1,1-trifluoro-, 1,1′-(1S)-[1,1′-binaphthalene]-2,2′-diyl ester
  • Methanesulfonic acid, trifluoro-, (1S)-[1,1′-binaphthalene]-2,2′-diyl ester
  • Methanesulfonic acid, trifluoro-, [1,1′-binaphthalene]-2,2′-diyl ester, (S)-
  • See more synonyms
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Found 6 products.

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(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate)

CAS:128544-05-8

Ref: 3B-B2231

1g87.00 €
Estimated delivery in United States, on Wednesday 9 Apr 2025
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Ref: IN-DA000Y5U

1g27.00 €
5g54.00 €
25g128.00 €
Estimated delivery in United States, on Wednesday 16 Apr 2025
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(S)-1,1'-Binaphthyl-2,2'-diyl bis(trifluoromethanesulphonate)

CAS:128544-05-8

Ref: 54-PC0615

1g37.00 €
5g34.00 €
25g121.00 €
100g414.00 €
500g1,754.00 €
Estimated delivery in United States, on Thursday 17 Apr 2025
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(S)-(+)-1,1''-Bi-2-naphthyl bis-trifluoromethanesulfonate

CAS:128544-05-8

Ref: 7W-GK5828

Undefined sizeTo inquire
Estimated delivery in United States, on Thursday 17 Apr 2025
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(S)-(+)-1,1'-Bi-2-naphthol bis(trifluoromethanesulfonate), 98%

CAS:128544-05-8

Ref: 08-08-0161

1g116.00 €
5g432.00 €
250mg42.00 €
Estimated delivery in United States, on Friday 9 May 2025
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(S)-(+)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)

CAS:128544-05-8

Ref: 3D-FB103912

1gDiscontinuedRequest information
2gDiscontinuedRequest information
5gDiscontinuedRequest information
10gDiscontinuedRequest information
500mgDiscontinuedRequest information
Discontinued product
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