CAS 1295-35-8

Bis(1,5-cyclooctadiene)nickel(0)

Description:

Bis(1,5-cyclooctadiene)nickel(0) is a coordination complex featuring nickel in its zero oxidation state, coordinated to two molecules of 1,5-cyclooctadiene (COD). This compound is characterized by its distinctive structure, where the nickel atom is centrally located and surrounded by the two COD ligands, which are cyclic hydrocarbons containing alternating double bonds. The presence of these ligands imparts unique properties, such as enhanced stability and solubility in organic solvents. Bis(1,5-cyclooctadiene)nickel(0) is often utilized in organometallic chemistry and catalysis, particularly in reactions involving olefins and in the formation of nickel-based catalysts. Its reactivity can be attributed to the ability of the nickel center to participate in various coordination and redox processes. Additionally, this compound is sensitive to air and moisture, necessitating careful handling and storage under inert atmospheres. Overall, its unique electronic and steric properties make it a valuable compound in synthetic organic chemistry and materials science.

Formula: C₁₆H₂₄Ni

InChI: InChI=1/2C8H12.Ni/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;/b2*2-1-,8-7-;

InChI key: InChIKey=JRTIUDXYIUKIIE-UHFFFAOYSA-N

SMILES: [Ni]123456([CH]7=[CH]1CC[CH]2=[CH]3CC7)[CH]8=[CH]4CC[CH]5=[CH]6CC8

Synonyms:

• (1Z,5Z)-cycloocta-1,5-diene-nickel (2:1)
• 1,5-Cyclooctadiene, nickel complex
• Bis((1,2,5,6-eta)-1,5-cyclooctadiene)nickel
• Bis(1,5-Ciclooctadieno)Niquel
• Bis(1,5-cyclooctadien)nickel
• Bis(1,5-cyclooctadiene)nickel
• Bis(cyclooctadiene)nickel
• Bis(cyclooctadiene)nickel(0)
• Bis(cyclooctadienyl)nickel
• Bis(η4-1,5-cyclooctadiene)nickel
• Bis(η⁴-1,5-cyclooctadiene)nickel
• Bis-1,5-cyclooctadienylnickel
• Bis[(1,2,5,6-η)-1,5-cyclooctadiene]nickel
• Ccris 5973
• Di(1,5-cyclooctadiene)nickel
• Dicyclooctadiene nickel
• Ni(COD)2
• Nickel bis(cyclooctadiene)
• Nickel dicyclooctadiene
• Nickel(COD)₂
• Nickel, bis((1,2,5,6-eta)-1,5-cyclooctadiene)-
• Nickel, bis(1,5-cyclooctadiene)-
• Nickel, bis[(1,2,5,6-η)-1,5-cyclooctadiene]-
• bis(1,5-cyclooctadiene)-nicke
• Bis(1,5-cyclooctadiene)nickel(0), 95+%
• Bis(1,5-cyclooctadiene) Nickel(O)
• Bis(1,5-cyclooctadiene)nickel(0),98+%
• BIS(1,5-CYCLOOCTADIENE)NICKEL(0)
• Bis(1,5-cyclooctadiene)nickel (0) (C8H12)2Ni

Bis(1,5-cyclooctadiene)nickel(0) (Wax encapsulated) (ca. 0.05mmol/capsule)

CAS: 1295-35-8

Formula: C₁₆H₂₄Ni

Color and Shape: White to Light yellow to Light orange powder to lump

Molecular weight: 275.06

Ref: 3B-B5417

Bis(1,5-cyclooctadiene)nickel(0), 96%

CAS: 1295-35-8

Catalyst for isomerization and hydrosilyltion of unsaturated compounds. Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and used to catalyze the addition of allyl phenyl sulf

Formula: C₁₆H₂₄Ni

Purity: 96%

Color and Shape: crystalline powder, Yellow to orange

Molecular weight: 275.06

Ref: 02-044157

Bis(1,5-cyclooctadiene)nickel (0), 98+%

CAS: 1295-35-8

Bis(1,5-cyclooctadiene)nickel (0), 98+%

Formula: (C₈H₁₂)₂Ni

Purity: 98+%

Color and Shape: yellow to orange xtl.

Molecular weight: 275.08

Ref: 08-28-0010

Bis(1,5-cyclooctadiene)nickel(0)

CAS: 1295-35-8

Formula: C₁₆H₂₄Ni

Purity: 98%

Color and Shape: Solid

Molecular weight: 275.0552

Ref: IN-DA0039OJ

Ni(COD)2

CAS: 1295-35-8

Ni(COD)2

Purity: 98%

Molecular weight: 275.06g/mol

Ref: 54-IN12370

BIS(1,5-CYCLOOCTADIENE)NICKEL(0)

CAS: 1295-35-8

Formula: C₁₆H₂₄Ni

Purity: 95%

Color and Shape: Solid, No data available.

Molecular weight: 275.061

Ref: 10-F513631

Bis(1,5-cyclooctadiene)nickel(0)

Controlled Product

CAS: 1295-35-8

Applications Bis(1,5-cyclooctadiene)nickel(0) is a reagent in the synthesis of self-assembled organometallic nickel complexes as catalysts for selective dimerization of ethylene into butene.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Boulens, P., et al.: Organometallics, 34, 1139 (2015)

Formula: C₁₆H₂₀Ni

Color and Shape: Neat

Molecular weight: 271.023

Ref: TR-B423990