CAS 1295-35-8
:Bis(1,5-cyclooctadiene)nickel(0)
Description:
Bis(1,5-cyclooctadiene)nickel(0) is a coordination complex featuring nickel in its zero oxidation state, coordinated to two molecules of 1,5-cyclooctadiene (COD). This compound is characterized by its distinctive structure, where the nickel atom is centrally located and surrounded by the two COD ligands, which are cyclic hydrocarbons containing alternating double bonds. The presence of these ligands imparts unique properties, such as enhanced stability and solubility in organic solvents. Bis(1,5-cyclooctadiene)nickel(0) is often utilized in organometallic chemistry and catalysis, particularly in reactions involving olefins and in the formation of nickel-based catalysts. Its reactivity can be attributed to the ability of the nickel center to participate in various coordination and redox processes. Additionally, this compound is sensitive to air and moisture, necessitating careful handling and storage under inert atmospheres. Overall, its unique electronic and steric properties make it a valuable compound in synthetic organic chemistry and materials science.
Formula:C16H24Ni
InChI:InChI=1/2C8H12.Ni/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;/b2*2-1-,8-7-;
InChI key:InChIKey=JRTIUDXYIUKIIE-UHFFFAOYSA-N
SMILES:[Ni]123456([CH]7=[CH]1CC[CH]2=[CH]3CC7)[CH]8=[CH]4CC[CH]5=[CH]6CC8
Synonyms:- (1Z,5Z)-cycloocta-1,5-diene-nickel (2:1)
- 1,5-Cyclooctadiene, nickel complex
- Bis((1,2,5,6-eta)-1,5-cyclooctadiene)nickel
- Bis(1,5-Ciclooctadieno)Niquel
- Bis(1,5-cyclooctadien)nickel
- Bis(1,5-cyclooctadiene)nickel
- Bis(cyclooctadiene)nickel
- Bis(cyclooctadiene)nickel(0)
- Bis(cyclooctadienyl)nickel
- Bis(η4-1,5-cyclooctadiene)nickel
- Bis(η<sup>4</sup>-1,5-cyclooctadiene)nickel
- Bis-1,5-cyclooctadienylnickel
- Bis[(1,2,5,6-η)-1,5-cyclooctadiene]nickel
- Ccris 5973
- Di(1,5-cyclooctadiene)nickel
- Dicyclooctadiene nickel
- Ni(COD)2
- Nickel bis(cyclooctadiene)
- Nickel dicyclooctadiene
- Nickel(COD)<sub>2</sub>
- Nickel, bis((1,2,5,6-eta)-1,5-cyclooctadiene)-
- Nickel, bis(1,5-cyclooctadiene)-
- Nickel, bis[(1,2,5,6-η)-1,5-cyclooctadiene]-
- bis(1,5-cyclooctadiene)-nicke
- Bis(1,5-cyclooctadiene)nickel(0), 95+%
- Bis(1,5-cyclooctadiene) Nickel(O)
- Bis(1,5-cyclooctadiene)nickel(0),98+%
- BIS(1,5-CYCLOOCTADIENE)NICKEL(0)
- Bis(1,5-cyclooctadiene)nickel (0) (C8H12)2Ni
- See more synonyms
Sort by
Purity (%)
0
100
|
0
|
50
|
90
|
95
|
100
Found 8 products.
Bis(1,5-cyclooctadiene)nickel(0) (Wax encapsulated) (ca. 0.05mmol/capsule)
CAS:Formula:C16H24NiColor and Shape:White to Light yellow to Light orange powder to lumpMolecular weight:275.06Bis(1,5-cyclooctadiene)nickel(0), 96%
CAS:Catalyst for isomerization and hydrosilyltion of unsaturated compounds. Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and used to catalyze the addition of allyl phenyl sulfFormula:C16H24NiPurity:96%Color and Shape:crystalline powder, Yellow to orangeMolecular weight:275.06Bis(1,5-cyclooctadiene)nickel (0), 98+%
CAS:Bis(1,5-cyclooctadiene)nickel (0), 98+%
Formula:(C8H12)2NiPurity:98+%Color and Shape:yellow to orange xtl.Molecular weight:275.08BIS(1,5-CYCLOOCTADIENE)NICKEL(0)
CAS:Formula:C16H24NiPurity:95%Color and Shape:Solid, No data available.Molecular weight:275.061Bis(1,5-cyclooctadiene)nickel(0)
CAS:Controlled ProductApplications Bis(1,5-cyclooctadiene)nickel(0) is a reagent in the synthesis of self-assembled organometallic nickel complexes as catalysts for selective dimerization of ethylene into butene.
Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package
References Boulens, P., et al.: Organometallics, 34, 1139 (2015)Formula:C16H20NiColor and Shape:NeatMolecular weight:271.023Bis(1,5-cyclooctadiene)nickel(0)
CAS:Formula:C16H24NiPurity:98%Color and Shape:SolidMolecular weight:275.0552
