CAS 130004-33-0: Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride

Description: Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride is a coordination complex featuring ruthenium as the central metal ion. This compound is characterized by its chiral ligand, which is derived from binaphthyl, providing it with potential applications in asymmetric catalysis. The presence of diphenylphosphine groups enhances the electron-donating ability of the ligand, facilitating the coordination with the ruthenium center. The p-cymene moiety contributes to the stability and solubility of the complex in organic solvents. As a ruthenium(II) complex, it typically exhibits a square planar geometry, which is common for d6 metal complexes. This compound is of interest in organic synthesis, particularly in reactions such as hydrogenation and cross-coupling, where it can act as a catalyst. Its chirality allows for the production of enantiomerically enriched products, making it valuable in the pharmaceutical and fine chemical industries. Safety and handling precautions should be observed due to the potential toxicity of the metal and organic components.

Formula: C₅₄H₄₆Cl₂P₂Ru

InChI: InChI=1/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

Synonyms:

• (S)-(-)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride
• Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride
• [(S,R)-(− )-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene] chloro(p-cymene)ruthenium chloride
• [RuCl(p-cymene)((S)-binap)]Cl
• (S)-RuCl[(p-cymene(BINAP)]Cl
• Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

[RuCl(p-cymene)((S)-binap)]Cl

CAS: 130004-33-0

• Formula: C₅₄H₄₆Cl₂P₂Ru
• Purity: >90.0%(HPLC)
• Color and Shape: White to Brown to Dark purple powder to crystal
• Molecular weight: 928.88

Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl

CAS: 130004-33-0

• Formula: C₅₄H₄₆ClP₂RuCl
• Color and Shape: orange pwdr.
• Molecular weight: 928.87

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE

CAS: 130004-33-0

• Formula: C₅₄H₄₆Cl₂P₂Ru
• Purity: 97%
• Color and Shape: Solid
• Molecular weight: 928.8666

(S)-RuCl[(p-cymene(BINAP)]Cl

CAS: 130004-33-0

• Purity: 98%
• Color and Shape: Solid
• Molecular weight: 928.87g/mol

(S)-RuCl[(p-cymene(BINAP)]Cl

CAS: 130004-33-0

• Purity: 98%
• Color and Shape: Solid
• Molecular weight: 930.9

[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride

CAS: 130004-33-0

• Formula: C₄₅H₃₅ClP₂Ru·C₁₀H₂₀·Cl
• Color and Shape: Neat
• Molecular weight: 949.949

Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride

CAS: 130004-33-0

Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride is a chiral ruthenium complex that is used as a catalyst for hydrogenations. …

• Formula: C₅₄H₄₆Cl₂P₂Ru
• Purity: Min. 95%
• Molecular weight: 928.87 g/mol