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CAS 130004-33-0

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Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride

Description:
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride is a coordination complex featuring ruthenium as the central metal ion. This compound is characterized by its chiral ligand, which is derived from binaphthyl, providing it with potential applications in asymmetric catalysis. The presence of diphenylphosphine groups enhances the electron-donating ability of the ligand, facilitating the coordination with the ruthenium center. The p-cymene moiety contributes to the stability and solubility of the complex in organic solvents. As a ruthenium(II) complex, it typically exhibits a square planar geometry, which is common for d6 metal complexes. This compound is of interest in organic synthesis, particularly in reactions such as hydrogenation and cross-coupling, where it can act as a catalyst. Its chirality allows for the production of enantiomerically enriched products, making it valuable in the pharmaceutical and fine chemical industries. Safety and handling precautions should be observed due to the potential toxicity of the metal and organic components.
Formula:C54H46Cl2P2Ru
InChI:InChI=1/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2
SMILES:c1ccc(cc1)P(c1ccccc1)c1ccc2ccccc2c1c1c2ccccc2ccc1P(c1ccccc1)c1ccccc1.CC(C)c1ccc(C)cc1.Cl.Cl.[Ru]
Synonyms:
  • (S)-(-)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride
  • Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride
  • [(S,R)-(− )-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene] chloro(p-cymene)ruthenium chloride
  • [RuCl(p-cymene)((S)-binap)]Cl
  • (S)-RuCl[(p-cymene(BINAP)]Cl
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
  • (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLO
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-
  • (RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-
  • See more synonyms
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