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CAS 13007-90-4

:

dicarbonylbis(triphenylphosphine)nickel

Description:
Dicarbonylbis(triphenylphosphine)nickel, with the CAS number 13007-90-4, is a coordination complex of nickel characterized by its unique structure and properties. This compound features a nickel center coordinated to two carbonyl (CO) ligands and two triphenylphosphine (PPh3) ligands. The presence of carbonyl groups imparts significant stability and influences the electronic properties of the nickel center, making it a valuable compound in organometallic chemistry. The triphenylphosphine ligands contribute to the steric bulk and solubility of the complex, enhancing its reactivity in various chemical reactions, including catalytic processes. Dicarbonylbis(triphenylphosphine)nickel is often utilized in organic synthesis and catalysis, particularly in reactions involving carbon-carbon bond formation. Its ability to facilitate electron transfer and stabilize reactive intermediates makes it an important compound in the development of new synthetic methodologies. Additionally, the compound's properties can be influenced by the choice of solvents and reaction conditions, making it versatile for various applications in both academic and industrial settings.
Formula:C38H30NiO2P2
InChI:InChI=1/2C18H15P.2CO.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;/h2*1-15H;;;/p+2
InChI key:InChIKey=SLFKPACCQUVAPG-UHFFFAOYSA-N
SMILES:[P]([Ni]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)(C#O)C#O)(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6
Synonyms:
  • (T-4)-Dicarbonylbis(triphenylphosphine)nickel
  • Bis(triphenylphosphine)dicarbonylnickel
  • Bis(triphenylphosphine)dicarbonylnickel(0)
  • Bis(triphenylphosphine)nickel dicarbonyl
  • Dicarbonyldi(triphenylphosphino)nickel
  • Nickel, dicarbonylbis(triphenylphosphine)-
  • Nickel, dicarbonylbis(triphenylphosphine)-, (T-4)-
  • Dicarbonylbis(triphenylphosphine)nickel
  • DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL
  • BIS(TRIPHENYLPHOSPHINE)NICKEL &
  • See more synonyms
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