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CAS 131457-46-0

:

(S,S)-2,2'-isopropylidene-bis(4-phenyl-2-oxazoline)

Description:
(S,S)-2,2'-isopropylidene-bis(4-phenyl-2-oxazoline) is a chiral ligand commonly used in asymmetric catalysis. This compound features a bis(oxazoline) structure, which consists of two oxazoline rings connected by an isopropylidene bridge. The presence of phenyl groups enhances its steric and electronic properties, making it effective in coordinating with metal centers, particularly transition metals, to facilitate enantioselective reactions. The (S,S) configuration indicates that both oxazoline rings possess the same stereochemistry, contributing to the ligand's ability to induce chirality in catalytic processes. This compound is typically utilized in the synthesis of chiral compounds, including pharmaceuticals and agrochemicals, due to its ability to form stable complexes with metals like copper and zinc. Its solubility in organic solvents and stability under various reaction conditions further enhance its utility in synthetic organic chemistry. Overall, (S,S)-2,2'-isopropylidene-bis(4-phenyl-2-oxazoline) is a valuable tool in the field of asymmetric synthesis.
Formula:C21H22N2O2
InChI:InChI=1/C21H22N2O2/c1-21(2,19-22-17(13-24-19)15-9-5-3-6-10-15)20-23-18(14-25-20)16-11-7-4-8-12-16/h3-12,17-18H,13-14H2,1-2H3/t17-,18-/m1/s1
SMILES:CC(C)(C1=N[C@H](CO1)c1ccccc1)C1=N[C@H](CO1)c1ccccc1
Synonyms:
  • (S)-()-2,2-Isopropylidenebis(4-phenyl-2-oxazoline)
  • (4S,4'S)-2,2'-propane-2,2-diylbis(4-phenyl-4,5-dihydro-1,3-oxazole)
  • (-)-2,2-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]propane
  • (S,S)-2,2-Bis(4-Phenyl-2-Oxazolin-2-Yl)Propane
  • (4S,4'S)-2,2'-(Propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole)
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