CAS 131614-43-2: Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Description:Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride, with CAS number 131614-43-2, is a chiral ruthenium complex that serves as a catalyst in various asymmetric synthesis reactions, particularly in the field of organic chemistry. This compound features a ruthenium center coordinated to a p-cymene ligand and a bidentate phosphine ligand derived from a chiral binaphthyl framework, which imparts stereochemical control in catalytic processes. The presence of the chloride ion indicates that it is a coordination complex, and the specific arrangement of the ligands contributes to its reactivity and selectivity in catalysis. This compound is often utilized in reactions such as hydrogenation and cross-coupling, where its chiral environment is crucial for producing enantiomerically enriched products. Its stability and effectiveness make it a valuable tool in synthetic organic chemistry, particularly in the development of pharmaceuticals and fine chemicals. Safety precautions should be observed when handling this compound, as with many transition metal complexes.
Formula:C58H54ClP2RuCl
InChI:InChI=1/C48H40P2.C10H14.2ClH.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-8(2)10-6-4-9(3)5-7-10;;;/h5-32H,1-4H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2
- Synonyms:
- (R)-RuCl[(p-cymene)(T-BINAP)]Cl
- Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
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[RuCl(p-cymene)((R)-tolbinap)]Cl
Ref: 3B-R0148
1g | 144.00 € | ||
200mg | 46.00 € |
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Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-tolbinap)]Cl
Ref: 08-44-0088
1g | 147.00 € | ||
5g | 276.00 € | ||
250mg | 53.00 € |
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Ruthenium(1+), [[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine]-P,P']chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-, (R)- (9CI)
Ref: IN-DA000ZHZ
1g | To inquire | ||
100mg | 310.00 € | ||
250mg | 491.00 € |
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Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-tolbinap)]Cl
Ref: 3D-GFA61443
1g | Discontinued | Request information | |
5g | Discontinued | Request information | |
10g | Discontinued | Request information | |
250mg | Discontinued | Request information | |
500mg | Discontinued | Request information |