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CAS 131766-06-8

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Rhodium, tetrakis[μ-[4-(1-methylethyl)-2-oxazolidinonato-N3:O2]]di-, (Rh-Rh), stereoisomer

Description:
Rhodium, tetrakis[μ-[4-(1-methylethyl)-2-oxazolidinonato-N3:O2]]di-, (Rh-Rh), is a coordination compound featuring rhodium as the central metal ion, coordinated with oxazolidinone ligands. This compound is characterized by its unique tetrakis structure, where two rhodium centers are bridged by four identical ligands, which contribute to its stability and reactivity. The oxazolidinonato ligands provide a chelating effect, enhancing the overall coordination environment around the rhodium atoms. The presence of the isopropyl group in the ligand structure introduces steric hindrance, which can influence the compound's stereochemistry and reactivity. This compound may exhibit interesting catalytic properties, particularly in organic transformations, due to the electronic and steric characteristics imparted by the ligands. Additionally, its stereoisomerism can lead to variations in physical and chemical properties, making it a subject of interest in coordination chemistry and catalysis research. Overall, this compound exemplifies the complexity and versatility of transition metal complexes in various chemical applications.
Formula:C24H40N4O8Rh2
InChI:InChI=1S/4C6H11NO2.2Rh/c4*1-4(2)5-3-9-6(8)7-5;;/h4*4-5H,3H2,1-2H3,(H,7,8);;/q;;;;2*+2/p-4
InChI key:InChIKey=GDIZWSQBHWMEEN-UHFFFAOYSA-J
SMILES:C(C)(C)C1[N-]2[Rh+2]345[Rh+2]([N-]6C(=O3)OCC6C(C)C)([N-]7C(=O4)OCC7C(C)C)(O=C8[N-]5C(C(C)C)CO8)O=C2OC1
Synonyms:
  • Rhodium, tetrakis[μ-[4-(1-methylethyl)-2-oxazolidinonato-N3:O2]]di-, (Rh-Rh), stereoisomer
  • 2-Oxazolidinone, 4-(1-methylethyl)-, rhodium complex, (S)-
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