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CAS 132388-65-9

:

N2-[(9H-Fluoren-9-ylmethoxy)carbonyl]-N-(triphenylmethyl)-L-glutamine 2,3,4,5,6-pentafluorophenyl ester

Description:
N2-[(9H-Fluoren-9-ylmethoxy)carbonyl]-N-(triphenylmethyl)-L-glutamine 2,3,4,5,6-pentafluorophenyl ester is a complex organic compound characterized by its unique structure, which includes a glutamine amino acid derivative modified with a fluorenylmethoxycarbonyl (Fmoc) protecting group and a triphenylmethyl (trityl) group. This compound is notable for its use in peptide synthesis, particularly in the protection of amino groups during the formation of peptide bonds. The presence of the pentafluorophenyl ester moiety enhances its reactivity and solubility in organic solvents, making it suitable for various synthetic applications. The fluorinated aromatic ring contributes to the compound's stability and can influence its electronic properties, potentially affecting its interactions in biological systems. Additionally, the compound's structure allows for selective cleavage of protecting groups under specific conditions, facilitating the synthesis of complex peptides. Overall, this compound exemplifies the intricate design often employed in the development of pharmaceutical intermediates and research reagents in organic chemistry.
Formula:C45H33F5N2O5
InChI:InChI=1S/C45H33F5N2O5/c46-37-38(47)40(49)42(41(50)39(37)48)57-43(54)35(51-44(55)56-26-34-32-22-12-10-20-30(32)31-21-11-13-23-33(31)34)24-25-36(53)52-45(27-14-4-1-5-15-27,28-16-6-2-7-17-28)29-18-8-3-9-19-29/h1-23,34-35H,24-26H2,(H,51,55)(H,52,53)/t35-/m0/s1
InChI key:InChIKey=OLYKAAWLZTVISS-DHUJRADRSA-N
SMILES:C(NC(CC[C@@H](C(OC1=C(F)C(F)=C(F)C(F)=C1F)=O)NC(OCC2C=3C(C=4C2=CC=CC4)=CC=CC3)=O)=O)(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
Synonyms:
  • <span class="text-smallcaps">L</span>-Glutamine, N<sup>2</sup>-[(9H-fluoren-9-ylmethoxy)carbonyl]-N-(triphenylmethyl)-, 2,3,4,5,6-pentafluorophenyl ester
  • <span class="text-smallcaps">L</span>-Glutamine, N<sup>2</sup>-[(9H-fluoren-9-ylmethoxy)carbonyl]-N-(triphenylmethyl)-, pentafluorophenyl ester
  • N-alpha-(9-fluorenylmethyloxycarbonyl)-N-gamma-trityl-L-glutamine pentafluorphenyl ester
  • N<sup>2</sup>-[(9H-Fluoren-9-ylmethoxy)carbonyl]-N-(triphenylmethyl)-<span class="text-smallcaps">L</span>-glutamine 2,3,4,5,6-pentafluorophenyl ester
  • pentafluorophenyl N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-N-trityl-L-glutaminate
  • L-Glutamine, N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-N-(triphenylmethyl)-, pentafluorophenyl ester
  • Fmoc-Gln(Trt)-OPfp
  • N2-[(9H-Fluoren-9-ylmethoxy)carbonyl]-N-(triphenylmethyl)-L-glutamine 2,3,4,5,6-pentafluorophenyl ester
  • L-Glutamine, N2-[(9H-fluoren-9-ylmethoxy)carbonyl]-N-(triphenylmethyl)-, 2,3,4,5,6-pentafluorophenyl ester
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