![Phenol, 2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl…](/_next/image/?url=https%3A%2Fstatic.cymitquimica.com%2Fcas-image%2Fthumb-webp%2F5527-phenol-22-1r-2r-12-cyclohexanediylbis-e-nitrilomethylidyne-bis-46-bis-11-dimethylethyl.webp&w=3840&q=75)
CAS 135616-40-9
:Phenol, 2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)-
Description:
The chemical substance known as "Phenol, 2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)-" with CAS number 135616-40-9 is a complex organic compound characterized by its phenolic structure and multiple functional groups. It features a cyclohexane backbone, which contributes to its three-dimensional conformation and steric properties. The presence of nitrile groups indicates potential reactivity, particularly in nucleophilic addition reactions. The bulky tert-butyl groups enhance its hydrophobic character and may influence its solubility in organic solvents. This compound may exhibit interesting biological activities due to its structural features, making it a candidate for various applications in materials science or medicinal chemistry. Additionally, the stereochemistry indicated by the (1R,2R) configuration suggests specific spatial arrangements that could affect its interactions with biological targets or other chemical species. Overall, this compound's unique structure and functional groups contribute to its potential utility in diverse chemical contexts.
Formula:C36H54N2O2
InChI:InChI=1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m1/s1
InChI key:InChIKey=FYNXDGNCEBQLGC-LQWPWIHBSA-N
SMILES:C(C)(C)(C)C1=C(O)C(/C=N/[C@H]2[C@H](/N=C/C3=C(O)C(C(C)(C)C)=CC(C(C)(C)C)=C3)CCCC2)=CC(C(C)(C)C)=C1
Synonyms:- (-)-N,N′-Bis((E)-3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
- (1R,2R)-(-)-1,2-Cyclohexanediamino-N N'-Bis(3,5-Di-T-Butylsalicylidene)
- (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-Bis-(3,5-Di-Tert-Butylsalicylidene)
- (1R,2R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
- (R,R)-(-)-N,N'-Bis(3,5-Di-T-Bu-Salicyl.)-1 ,2-Cyclohexandiam.
- (R,R)-(-)-N,N'-Bis(3,5-di-t-bu-salicyl.)-1,2-cyclohexanedia
- (R,R)-(-)-N,N'-Bis(3.5-Di-T-Butylsalicylidene)-1,2-Cyclohexanediamine
- (R,R)-2,2′-[(1,2-Cyclohexanediyl)bis(nitrilomethylidyne)]bis[4,6-di(tert-butyl)phenol]
- (R,R)-Jacobsen Ligand
- (R,R)-Jacobsen'S Ligand
- 2,2′-[(1R,2R)-1,2-Cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenol
- 6,6'-[(1R,2R)-cyclohexane-1,2-diylbis(iminomethylylidene)]bis(2,4-di-tert-butylcyclohexa-2,4-dien-1-one)
- Phenol, 2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(E)-nitrilomethylidyne]]bis[4,6-bis(1,1-dimethylethyl)-
- Phenol, 2,2′-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)-, [1R-[1α(E),2β(E)]]-
- See more synonyms
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Found 7 products.
(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
CAS:Formula:C36H54N2O2Purity:>98.0%(HPLC)(N)Color and Shape:White to Yellow to Yellow green powder to crystalMolecular weight:546.846,6'-((1E,1'E)-(((1R,2R)-Cyclohexane-1,2-diyl)bis(azanylylidene))bis(methanylylidene))bis(2,4-di-tert-butylphenol)
CAS:Purity:98%Color and Shape:SolidMolecular weight:546.84(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
CAS:Formula:C36H54N2O2Purity:98%Color and Shape:SolidMolecular weight:546.8262(R,R)-(-)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine
CAS:<p>(R,R)-(-)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine</p>Purity:98%Molecular weight:546.83g/mol(R,R)-(-)-N,N’-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
CAS:Controlled Product<p>Applications (R,R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a versatile ligand used in the preparation of Jacobsen's catalyst.<br>References Jacobsen, E.N. et al.: J. Am. Chem. Soc., 113, 7063 (1991); Deng, L. et al.: J. Org. Chem., 57, 4320 (1992);<br></p>Formula:C36H54N2O2Color and Shape:NeatMolecular weight:546.83RR,R)-(-)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
CAS:<p>RR,R)-(-)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a coordination compound that is used as a catalyst in organic chemistry. It has been shown to catalyze the reaction of benzaldehyde with nitroethane to give phenylamine. RR,R)-(-)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine also catalyzes the reaction of cyclohexanol with nitroethane to give phenylethylene. The selectivity of this catalyst depends on the site of adsorption and the ligand. This compound has been shown to be electrocatalytic by promoting the oxidation of anilines at a platinum electrode in water solution with an applied potential.</p>Formula:C36H54N2O2Purity:Min. 95%Molecular weight:546.83 g/mol
