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CAS 135707-05-0

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Copper(l) (hexafluoroacetylacetonato)trimethylphosphine

Description:
Copper(I) hexafluoroacetylacetonato(trimethylphosphine) is a coordination compound featuring copper in the +1 oxidation state, coordinated by hexafluoroacetylacetonate (hfac) ligands and trimethylphosphine. This compound typically exhibits a square planar geometry around the copper center, which is characteristic of many copper(I) complexes. The hexafluoroacetylacetonate ligand is a bidentate ligand, providing strong chelation due to its electron-withdrawing fluorine atoms, which enhances the stability of the complex. Trimethylphosphine acts as a neutral ligand, contributing to the overall electron density around the copper center. The compound is often characterized by its distinct color, solubility in organic solvents, and potential applications in catalysis and materials science. Its properties, such as thermal stability and reactivity, can be influenced by the steric and electronic effects of the ligands. As with many metal complexes, safety precautions should be taken when handling this compound due to potential toxicity associated with copper and phosphine derivatives.
Formula:C8H10CuF6O2P
InChI:InChI=1/C5H2F6O2.C3H9P.Cu/c6-4(7,8)2(12)1-3(13)5(9,10)11;1-4(2)3;/h1,12H;1-3H3;/q;;+1/p-1/b2-1-;;
SMILES:C(=C(C(F)(F)F)O)C(=O)C(F)(F)F.CP(C)C.[Cu]
Synonyms:
  • Cuprous
  • (Z)-1,1,1,5,5,5-hexafluoro-4-oxo-pent-2-en-2-olate
  • Trimethylphosphane
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