CAS 1365531-85-6

1,1′-[(1S)-4,4′,6,6′-Tetramethoxy[1,1′-biphenyl]-2,2′-diyl]bis[1,1-bis[3,5-bis(trifluoromethyl)phenyl]phosphine

Description:

The chemical substance known as 1,1′-[(1S)-4,4′,6,6′-Tetramethoxy[1,1′-biphenyl]-2,2′-diyl]bis[1,1-bis[3,5-bis(trifluoromethyl)phenyl]phosphine] is a complex organophosphorus compound characterized by its unique structural features, including multiple methoxy and trifluoromethyl groups. This compound exhibits significant steric hindrance due to its bulky substituents, which can influence its reactivity and interactions with other molecules. The presence of phosphine groups suggests potential applications in catalysis, particularly in transition metal-catalyzed reactions, where phosphines often serve as ligands. Additionally, the trifluoromethyl groups enhance the lipophilicity and electronic properties of the molecule, potentially affecting its solubility and stability in various solvents. The chirality indicated by the (1S) configuration may also impart specific optical properties, making it of interest in asymmetric synthesis. Overall, this compound's intricate structure and functional groups position it as a valuable candidate for research in organic synthesis and materials science.

Formula: C₄₈H₂₈F₂₄O₄P₂

InChI: InChI=1S/C48H28F24O4P2/c1-73-29-17-35(75-3)39(37(19-29)77(31-9-21(41(49,50)51)5-22(10-31)42(52,53)54)32-11-23(43(55,56)57)6-24(12-32)44(58,59)60)40-36(76-4)18-30(74-2)20-38(40)78(33-13-25(45(61,62)63)7-26(14-33)46(64,65)66)34-15-27(47(67,68)69)8-28(16-34)48(70,71)72/h5-20H,1-4H3

InChI key: InChIKey=JDKXXRZDVSJSNQ-UHFFFAOYSA-N

SMILES: P(C1=C(C(OC)=CC(OC)=C1)C2=C(P(C3=CC(C(F)(F)F)=CC(C(F)(F)F)=C3)C4=CC(C(F)(F)F)=CC(C(F)(F)F)=C4)C=C(OC)C=C2OC)(C5=CC(C(F)(F)F)=CC(C(F)(F)F)=C5)C6=CC(C(F)(F)F)=CC(C(F)(F)F)=C6

Synonyms:

• Phosphine, 1,1′-[(1S)-4,4′,6,6′-tetramethoxy[1,1′-biphenyl]-2,2′-diyl]bis[1,1-bis[3,5-bis(trifluoromethyl)phenyl]-
• 1,1′-[(1S)-4,4′,6,6′-Tetramethoxy[1,1′-biphenyl]-2,2′-diyl]bis[1,1-bis[3,5-bis(trifluoromethyl)phenyl]phosphine
• (S)-2,2'-Bis[bis(3,5-trifluoromethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl
• (S)-2,2'-Bis[bis(3,5-trifluoromethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl, min. 97% (S)-BTFM-Garphos(TM)
• (S)-2,2'-Bis[bis(3,5-trifluoroMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, 97+%
• (S)-2,2'-Bis[bis(3,5-trifluoroMethylphenyl)phosphino]-4,4',6,6'-tetraMethoxybiphenyl, Min. 97% (S)-BTFM-Garphos

(S)-BTFM-Garphos

CAS: 1365531-85-6

(S)-BTFM-Garphos

Purity: 97%

Molecular weight: 760.44g/mol

Ref: 54-PC110443

(R)-(4,4′,6,6′-TETRAMETHOXY-1,1′-BIPHENYL-2,2′-DIYL)BIS(BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)PHOSPHINE)

CAS: 1365531-85-6

Purity: 97%

Molecular weight: 1186.656982

Ref: 10-F847896

(S)-2,2'-Bis[bis(3,5-trifluoromethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl, min. 97% (S)-BTFM-Garphos™

CAS: 1365531-85-6

(S)-2,2'-Bis[bis(3,5-trifluoromethylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl, min. 97% (S)-BTFM-Garphos™

Formula: C₄₈H₂₈F₂₄O₄P₂

Purity: min. 97%

Color and Shape: pale yellow solid

Molecular weight: 1186.64

Ref: 08-15-1664