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CAS 136705-65-2

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1,2-Bis[(2R,5R)-2,5-diisopropylphospholan-1-yl]benzene

Description:
1,2-Bis[(2R,5R)-2,5-diisopropylphospholan-1-yl]benzene, with the CAS number 136705-65-2, is a chemical compound characterized by its unique structure that features a benzene ring substituted with two phospholane groups. The phospholane moieties are chiral, specifically in the (2R,5R) configuration, which contributes to the compound's stereochemical properties. This compound is notable for its potential applications in organometallic chemistry and catalysis, particularly due to the presence of phosphorus, which can facilitate various chemical reactions. The diisopropyl groups enhance the steric bulk around the phosphorus atoms, influencing the reactivity and selectivity in catalytic processes. Additionally, the compound's solubility and stability can be affected by the bulky substituents, making it suitable for specific synthetic applications. Overall, 1,2-Bis[(2R,5R)-2,5-diisopropylphospholan-1-yl]benzene exemplifies the intersection of organic and inorganic chemistry, showcasing the importance of ligand design in coordination chemistry.
Formula:C26H44P2
InChI:InChI=1S/C26H44P2/c1-17(2)21-13-14-22(18(3)4)27(21)25-11-9-10-12-26(25)28-23(19(5)6)15-16-24(28)20(7)8/h9-12,17-24H,13-16H2,1-8H3/t21-,22-,23-,24-/m1/s1
InChI key:InChIKey=RBVGOQHQBUPSGX-MOUTVQLLSA-N
SMILES:C(C)(C)[C@@H]1[P@]([C@@H]([C@@H](C)C)CC1)C2=C(C=CC=C2)[P@]3[C@@H](C(C)C)CC[C@@H]3[C@@H](C)C
Synonyms:
  • (2R,2'R,5'R)-1,1'-benzene-1,2-diylbis[2,5-di(propan-2-yl)phospholane]
  • (2R,2′R,5R,5′R)-1,1′-(1,2-Phenylene)bis[2,5-bis(1-methylethyl)phospholane
  • (R,R)-Isopropyl-DuPHOS
  • (R,R)-i-Pr-DuPHOS
  • 1,2-Bis[(2R,5R)-2,5-diisopropylphospholan-1-yl]benzene
  • Phospholane, 1,1′-(1,2-phenylene)bis[2,5-bis(1-methylethyl)-, (2R,2′R,5R,5′R)-
  • Phospholane, 1,1′-(1,2-phenylene)bis[2,5-bis(1-methylethyl)-, [2R-[1(2′R*,5′R*),2α,5β]]-
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