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CAS 1375325-68-0

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Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-amino-1,1'-biphenyl-2-yl)palladium(II)

Description:
Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-amino-1,1'-biphenyl-2-yl)palladium(II) is a palladium complex notable for its application in catalysis, particularly in cross-coupling reactions such as Suzuki and Heck reactions. This compound features a palladium center coordinated with a chloro ligand and a bidentate ligand system that includes a phosphine and an amine, enhancing its reactivity and selectivity. The presence of bulky dicyclohexylphosphino groups contributes to its steric properties, which can influence the catalytic activity and substrate scope. The biphenyl moieties provide additional electronic effects that can stabilize the palladium center and facilitate the activation of substrates. This compound is typically characterized by its solubility in organic solvents, stability under inert conditions, and its ability to undergo oxidative addition and reductive elimination processes, which are fundamental to its catalytic function. Overall, it represents a significant class of organometallic compounds used in synthetic organic chemistry.
Formula:C42H53ClNO2PPd
InChI:InChI=1S/C30H43O2P.C12H10N.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H;/q;-1;;+2/p-1
InChI key:InChIKey=NVVXJVMOIGXUGC-UHFFFAOYSA-M
SMILES:[P]([Pd+2]1([Cl-])[C-]=2C(C=3C([NH2]1)=CC=CC3)=CC=CC2)(C4=C(C=CC=C4)C5=C(OC(C)C)C=CC=C5OC(C)C)(C6CCCCC6)C7CCCCC7
Synonyms:
  • Palladium, [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC][[2′,6′-bis(1-methylethoxy)[1,1′-biphenyl]-2-yl]dicyclohexylphosphine-κP]chloro-
  • RuPhos Palladacycle
  • RuPhos Pd G2
  • [2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC][[2′,6′-bis(1-methylethoxy)[1,1′-biphenyl]-2-yl]dicyclohexylphosphine-κP]chloropalladium
  • Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [RuPhos Palladacycle]
  • 2nd Generation RuPhos Precatalyst
  • (2'-Amino-[1,1'-biphenyl]-2-yl)(dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphoranyl)palladium(III) chloride
  • dicyclohexyl-[2-(2,6-diisopropoxyphenyl)phenyl]phosphane
  • [2-(2-Aminophenyl)phenyl]-chloro-palladium
  • See more synonyms
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