CAS 13811-71-7

(-)-Diethyl tartrate

Description:

(-)-Diethyl tartrate is an organic compound that belongs to the class of tartrates, which are esters derived from tartaric acid. It is a chiral molecule, exhibiting optical activity due to the presence of multiple stereocenters, specifically existing as one of the enantiomers of diethyl tartrate. This compound is typically a colorless to pale yellow liquid with a characteristic fruity odor. It is soluble in organic solvents such as ethanol and ether but has limited solubility in water. (-)-Diethyl tartrate is often used in asymmetric synthesis and as a chiral auxiliary in organic chemistry, facilitating the production of enantiomerically pure compounds. Additionally, it can serve as a reagent in various chemical reactions, including the synthesis of pharmaceuticals and agrochemicals. Its properties, such as boiling point and density, can vary depending on the specific conditions and purity of the sample. Safety data indicates that it should be handled with care, as it may cause irritation upon contact with skin or eyes.

Formula: C₈H₁₄O₆

InChI: InChI=1S/C8H14O6/c1-3-13-7(11)5(9)6(10)8(12)14-4-2/h5-6,9-10H,3-4H2,1-2H3/t5-,6-/m0/s1

InChI key: InChIKey=YSAVZVORKRDODB-WDSKDSINSA-N

SMILES: [C@H]([C@@H](C(OCC)=O)O)(C(OCC)=O)O

Synonyms:

• (-)-Diethyl D-tartarate
• (-)-Diethyl tartrate
• (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
• (2S,3S)-Diethyl tartrate
• (S,S)-Diethyl tartrate
• <span class="text-smallcaps">D</span>-(-)-Diethyl tartrate
• <span class="text-smallcaps">D</span>-(-)-Tartaric acid diethyl ester
• <span class="text-smallcaps">D</span>-Diethyl tartarate
• <span class="text-smallcaps">D</span>-Ethyl tartrate
• Butanedioic acid, 2,3-dihydroxy-, 1,4-diethyl ester, (2S,3S)-
• Butanedioic acid, 2,3-dihydroxy-, diethyl ester, [S-(R*,R*)]-
• D-(-)Det
• Diethyl (-)-<span class="text-smallcaps">D</span>-tartrate
• Diethyl (2S,3S)-(-)-tartrate
• Diethyl (S,S)-(-)-tartrate
• Tartaric acid, diethyl ester, (-)-
• D-Tartaric acid diethyl ester
• Diethyl-D-tartrate

(-)-Diethyl D-tartrate, 99%

CAS: 13811-71-7

Diethyl D(-)-tartrate is mainly used in chiral pharmaceuticals, chiral intermediates and chiral catalysts. It can be used with titanium in enolic asymmetric epoxidization. The compound d-alpha-tocopherol is the principal compound present in natural vitamin E sources. At present, d-alpha-tocopherol a

Formula: C₈H₁₄O₆

Purity: 99%

Color and Shape: Clear colorless, Liquid or viscous liquid

Molecular weight: 206.19

Ref: 02-A17992

(2S,3S)-Diethyl 2,3-dihydroxysuccinate

CAS: 13811-71-7

Formula: C₈H₁₄O₆

Purity: 95%

Color and Shape: Liquid

Molecular weight: 206.1932

Ref: IN-DA0034OH

(-)-Diethyl D-tartrate

CAS: 13811-71-7

(-)-Diethyl D-tartrate

Purity: 99%

Color and Shape: Liquid

Molecular weight: 206.19g/mol

Ref: 54-OR0908

Diethyl-D-tartrate

CAS: 13811-71-7

Formula: C₈H₁₄O₆

Molecular weight: 206.19

Ref: 7W-GE5449

Diethyl D-(-)-Tartrate

CAS: 13811-71-7

Formula: C₈H₁₄O₆

Purity: >97.0%(GC)

Color and Shape: Colorless to Light yellow clear liquid

Molecular weight: 206.19

Ref: 3B-T1195

(2S,3S)-Diethyl 2,3-dihydroxysuccinate

CAS: 13811-71-7

Formula: C₈H₁₄O₆

Purity: 98%

Color and Shape: Clear Liquid or Viscous Liquid

Molecular weight: 206.194

Ref: 10-F404742

Diethyl D-(-)-Tartrate

CAS: 13811-71-7

Applications Diethyl D-(-)-Tartrate is used as a chiral reagent in a host of chemical reactions, suhc as marin toxin and antitumor agent phorboxazole A, or asymmetric syntheses of S,S-dialkyl-substituted sulfoximines.
References Pandey, A. et al.: Synthesis, 23, 3827 (2011); Kuntiyong, P. et al.: Org. Biomol. Chem., 10, 7884 (2012);

Formula: C₈H₁₄O₆

Color and Shape: Neat

Molecular weight: 206.1932

Ref: TR-D445045