CAS 138124-32-0: (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-Butylsalicylidene)-1,2-Cyclohexanediamino-manganese(III) chloride

Description: (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride is a coordination compound featuring a manganese center coordinated to a bidentate ligand derived from a chiral diamine and salicylaldehyde derivatives. This compound is characterized by its significant steric hindrance due to the presence of bulky tert-butyl groups on the salicylidene moieties, which can influence its reactivity and selectivity in catalytic processes. The manganese(III) oxidation state is notable for its ability to participate in redox reactions, making this compound of interest in catalysis and materials science. The chirality of the ligand imparts potential enantioselectivity in reactions, which is valuable in asymmetric synthesis. Additionally, the chloride ion serves as a counterion, stabilizing the complex. Its unique structural features and properties make it a subject of study in coordination chemistry and its applications in catalysis, particularly in organic transformations.

Formula: C₃₆H₅₂ClMnN₂O₂

InChI: InChI=1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/t29-,30-;;/m1../s1

InChI key: InChIKey=LJVAWOSDJSQANR-SEILFYAJSA-K

SMILES: [Cl-][Mn+3]123[O-]C4=C(C=C(C=C4C(C)(C)C)C(C)(C)C)C=[N]3C5CCCCC5[N]2=CC=6C=C(C=C(C6[O-]1)C(C)(C)C)C(C)(C)C

Synonyms:

• (+)-Bis(3,5-Di-T-Bu-Salicyl.)-1,2-Cyclo-Hexanediamino-Mn Cl
• (-)-Bis(3,5-Di-T-Bu-Salicyl.)-1,2-Cyclo-
• (-)-Chloro{(1R,2R)-4,4′,6,6′-tetra-tert-butyl-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III)
• (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]MANGANESE(III)CHLORIDE
• (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-BIS(3,5-DI-T-Butylsalicylidene)]manganese (III) chloride
• (R,R)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-diaminocyclohexylmanganese(III) chloride
• (R,R)-(-)-N,N'-BIS(3.5-DI-T-Butylsalicylidene)-1,2-CYCLOHEXANEDIAMINE-manganese (III) chloride
• (R,R)-(-)-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino manganese(II) chloride
• (R,R)-Jacobsen Cat.
• (R,R)-Jacobsen Catalyst
• (R,R)-Jacobsen'S Catalyst
• (R,R)-Jacobsen'S Catalyst Manganese(Iii) Chloride Complex
• (R,R)-[N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
• (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-Butylsalicylidene)-1,2-Cyclohexanediamino-MANGANESE(III) CHLORIDE
• (S,S)-Jacobsen Cat.
• (S,S)-Jacobsen Catalyst
• (S,S)-Jacobsen'S Catalyst
• (S,S)-Jacobsen'S Catalyst Manganese(Iii) Chloride Complex
• (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL-IDENE)-1,2-Cyclohexanediamino-MN-CL
• (SP-5-13)-Chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese
• 2,2'-{(1R,2R)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-trichloromanganese (1:1)
• 2,2'-{(1S,2S)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-trichloromanganese (1:1)
• Jacobsen'S Catalyst
• Manganese, chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, (SP-5-13)-
• Manganese, chloro[[2,2′-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)phenolato]](2-)-N,N′,O,O′]-, [SP-5-13-(1R-trans)]-
• Manganese, chloro[[2,2′-[1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, [SP-5-13-(1R-trans)]-
• chloro[[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]manganese

(1R,2R)-(-)-[1,2-Cyclo­hexanediamino-N,N'-bis(3,5-di-t-butyl­salicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.

CAS: 138124-32-0

(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese (III) chloride, 98% (R,R)-Jacobsen Cat.

• Formula: C₃₆H₅₂ClMnN₂O₂
• Purity: 98%
• Color and Shape: brown pwdr.
• Molecular weight: 635.22

(R,R)-(-)-N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2- cyclohexanediaminomanganese(III) chloride

CAS: 138124-32-0

• Formula: C₃₆H₅₂ClMnN₂O₂
• Purity: 98%
• Color and Shape: Solid
• Molecular weight: 635.2013290000003

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride

CAS: 138124-32-0

• Purity: 98%
• Molecular weight: 635.21g/mol

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

CAS: 138124-32-0

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. …

• Formula: C₃₆H₅₄ClMnN₂O₂
• Color and Shape: Dark brown, Powder or crystals and/or chunks
• Molecular weight: 637.23

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) Chloride

CAS: 138124-32-0

• Formula: C₃₆H₅₂ClMnN₂O₂
• Purity: >98.0%(HPLC)
• Color and Shape: Orange to Brown powder to crystal
• Molecular weight: 635.21

(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

CAS: 138124-32-0

Please enquire for more information about (R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride including the price, delivery time and more …

• Formula: C₃₆H₅₂ClMnN₂O₂
• Purity: Min. 95%
• Color and Shape: Powder
• Molecular weight: 635.2 g/mol