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CAS 138984-26-6

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DIRHODIUM (II) TETRAKIS(CAPROLACTAM)

Description:
Dirhodium (II) tetrakis(caprolactam) is a coordination compound featuring a dirhodium core with four caprolactam ligands. This compound is characterized by its unique structure, where the rhodium centers are in a low oxidation state, specifically +2, which is relatively rare for transition metals. The caprolactam ligands, derived from the cyclic amide of caproic acid, contribute to the stability and solubility of the complex in various solvents. Dirhodium complexes are known for their catalytic properties, particularly in organic synthesis, where they can facilitate various reactions, including C-H activation and cyclopropanation. The presence of the caprolactam ligands enhances the electronic properties of the metal centers, potentially influencing reactivity and selectivity in catalytic processes. Additionally, dirhodium complexes often exhibit interesting optical properties and can be studied using spectroscopic techniques. Overall, dirhodium (II) tetrakis(caprolactam) represents a fascinating area of research in coordination chemistry and catalysis.
Formula:C24H40N4O4Rh2
InChI:InChI=1/4C6H11NO.2Rh/c4*8-6-4-2-1-3-5-7-6;;/h4*1-5H2,(H,7,8);;/q;;;;2*+2/p-4/rC24H40N4O4Rh2/c1-5-13-21-25(17-9-1)33-26-18-10-2-6-14-22(26)32-34(33,29-21,27-19-11-3-7-15-23(27)30-33)28-20-12-4-8-16-24(28)31-33/h1-20H2
SMILES:C1CCC(=NCC1)O.C1CCC(=NCC1)O.C1CCC(=NCC1)O.C1CCC(=NCC1)O.[Rh].[Rh]
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