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CAS 14040-05-2

:

Bis(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Copper(II)

Description:
Bis(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Copper(II), commonly referred to as Cu(TMHD)2, is a coordination compound featuring copper in a +2 oxidation state. This substance is characterized by its chelation with two bidentate ligands, 2,2,6,6-tetramethyl-3,5-heptanedione, which provide a stable environment for the copper ion. The compound typically appears as a blue or green solid and is soluble in organic solvents, making it useful in various applications, including catalysis and as a precursor in the synthesis of copper-containing materials. Cu(TMHD)2 exhibits thermal stability and can decompose at elevated temperatures, releasing copper oxides. Its coordination geometry is generally square planar or distorted octahedral, depending on the environment. The compound is of interest in fields such as materials science and organic synthesis due to its ability to facilitate reactions involving copper. Safety precautions should be taken when handling this compound, as it may pose health risks if ingested or inhaled.
Formula:C22H40CuO4
InChI:InChI=1/2C11H20O2.Cu/c2*1-10(2,3)8(12)7-9(13)11(4,5)6;/h2*7H2,1-6H3;
SMILES:CC(C)(C)C(=O)CC(=O)C(C)(C)C.CC(C)(C)C(=O)CC(=O)C(C)(C)C.[Cu]
Synonyms:
  • Copper Bis(Dipivaloylmethanate)
  • Copper Bis(2,2,6,6-Tetramethyl-3,5-Heptanedionate)
  • Copper Bis(2,2,6,6-Tetramethylheptane-3,5-Dione)
  • Copper(Ii) Bis(2,2,6,6-Tetramethyl-3,5-Heptanedionate)
  • Copper Ii 2,2,6,6-Tetramethyl-3,5-Heptanedionate
  • Cu(Tmhd)2
  • Copper(Ii) Dipivaloylmethanate
  • Copper(Ii)-Thd
  • 2,2,6,6-Tetramethylheptane-3,5-Dione-Copper (2:1)
  • Bis(dipivaloylmethanato)copper
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